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Valence shell electron pair repulsion (VSEPR) theory (/ ˈ v ɛ s p ər, v ə ˈ s ɛ p ər / VESP-ər, [1]: 410 və-SEP-ər [2]) is a model used in chemistry to predict the geometry of individual molecules from the number of electron pairs surrounding their central atoms. [3]
As described by the VSEPR model, the five valence electron pairs on the central atom form a trigonal bipyramid in which the three lone pairs occupy the less crowded equatorial positions and the two bonded atoms occupy the two axial positions at the opposite ends of an axis, forming a linear molecule.
More deviations from the ideal VSEPR model were found in the solid state structures due to strong cation-anion interactions, which also complicates interpretation of vibrational spectroscopic data. In all known structures of the polyhalogen anion salts, the anions make very close contact, via halogen bridges, with the counter-cations. [4]
According to VSEPR theory, T-shaped geometry results when three ligands and two lone pairs of electrons are bonded to the central atom, written in AXE notation as AX 3 E 2. The T-shaped geometry is related to the trigonal bipyramidal molecular geometry for AX 5 molecules with three equatorial and two axial ligands.
In a crystal structure the coordination geometry of an atom is the geometrical pattern of coordinating atoms where the definition of coordinating atoms depends on the bonding model used. [1] For example, in the rock salt ionic structure each sodium atom has six near neighbour chloride ions in an octahedral geometry and each chloride has ...
3D model of a (uniform) square antiprism. In geometry, the square antiprism is the second in an infinite family of antiprisms formed by an even-numbered sequence of triangle sides closed by two polygon caps. It is also known as an anticube. [1] If all its faces are regular, it is a semiregular polyhedron or uniform polyhedron.
Despite continued heated debate on which model more accurately depict the true bonding scheme of molecules, scientists now view MO and VB theories as complementary and teammates. With the development of modern high speed computers and advanced molecular modeling programs, both MO and VB theories are used widely today, though for generally ...
In chemistry, ligand close packing theory (LCP theory), sometimes called the ligand close packing model describes how ligand – ligand repulsions affect the geometry around a central atom. [1] It has been developed by R. J. Gillespie and others from 1997 onwards [ 2 ] and is said to sit alongside VSEPR [ 1 ] which was originally developed by R ...