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In chemistry, initiation is a chemical reaction that triggers one or more secondary reactions. Initiation creates a reactive centre on a molecule which produces a chain reaction . [ 1 ] The reactive centre generated by initiation is usually a radical , but can also be cations or anions . [ 2 ]
Initiation steps are classified according to the way that energy is provided: thermal initiation, high energy initiation, and chemical initiation, etc. Thermal initiation uses molecular thermal motion to dissociate a molecule and form active centers. High energy initiation refers to the generation of chain carriers by radiation.
Nuclear chemistry is a sub-discipline of chemistry that involves the chemical reactions of unstable and radioactive elements where both electronic and nuclear changes can occur. The substance (or substances) initially involved in a chemical reaction are called reactants or reagents.
Diverse methods are employed to manipulate the initiation, propagation, and termination rates during chain polymerization. A related issue is temperature control, also called heat management, during these reactions, which are often highly exothermic. For example, for the polymerization of ethylene, 93.6 kJ of energy are released per mole of ...
For chain-growth polymerization, the overall activation energy is = +, where i, p and t refer respectively to initiation, propagation and termination steps. The propagation step normally has a very small activation energy, so that the overall value is negative if the activation energy for termination is larger than that for initiation.
Thermionic emission is the liberation of charged particles from a hot electrode whose thermal energy gives some particles enough kinetic energy to escape the material's surface. The particles, sometimes called thermions in early literature, are now known to be ions or electrons.
Initiation (formation of active particles or chain carriers, often free radicals, in either a thermal or a photochemical step) Propagation (may comprise several elementary steps in a cycle, where the active particle through reaction forms another active particle which continues the reaction chain by entering the next elementary step).
Chemical reactions involving thermal runaway are also called thermal explosions in chemical engineering, or runaway reactions in organic chemistry.It is a process by which an exothermic reaction goes out of control: the reaction rate increases due to an increase in temperature, causing a further increase in temperature and hence a further rapid increase in the reaction rate.