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Peroxymonosulfuric acid, also known as persulfuric acid, peroxysulfuric acid is the inorganic compound with the formula H 2 SO 5. It is a white solid. It is a component of Caro's acid, which is a solution of peroxymonosulfuric acid in sulfuric acid containing small amounts of water. [4] Peroxymonosulfuric acid is a very strong oxidant (E 0 = +2 ...
It is the potassium salt of peroxymonosulfuric acid. Potassium peroxymonosulfate per se is rarely encountered. It is often confused with the triple salt 2KHSO 5 ·KHSO 4 ·K 2 SO 4, known as Oxone. The standard electrode potential for potassium peroxymonosulfate is +1.81 V with a half reaction generating the hydrogen sulfate (pH = 0): [3]
A typical mixture is 3 parts of concentrated sulfuric acid and 1 part of 30 wt. % hydrogen peroxide solution; [1] other protocols may use a 4:1 or even 7:1 mixture. A closely related mixture, sometimes called "base piranha", is a 5:1:1 mixture of water, ammonia solution (NH 4 OH, or NH 3 (aq)), and 30% hydrogen peroxide.
Peroxymonosulfuric acid (Caro's acid) is probably the most important inorganic peracid, at least in terms of its production scale. [1] It is used for the bleaching of pulp and for the detoxification of cyanide in the mining industry. It is produced by treating sulfuric acid with hydrogen peroxide. Peroxymonophosphoric acid (H 3 PO 5) is ...
1 Compounds containing peroxomonosulfate. ... Chemical formula. O 5 S −2: Molar mass: 112.06 g·mol −1 Conjugate acid: Peroxymonosulfuric acid:
A persulfate (sometimes known as peroxysulfate or peroxodisulfate) [1] is a compound containing the anions SO 2− 5 or S 2 O 2− 8. [2] The anion SO 2− 5 contains one peroxide group per sulfur center, whereas in S 2 O 2− 8, the peroxide group bridges the sulfur atoms. In both cases, sulfur adopts the normal tetrahedral geometry typical ...
Polysulfuric acids including disulfuric acid (pyrosulfuric acid) H 2 SO 4 ·nSO 3 +6 Disulfate (commonly known as pyrosulfate), S 2 O 2− 7 and trisulfate, S 3 O 2− 10: Pure disulfuric acid melts at 36 °C. Present in fuming sulfuric acid, oleum. Examples known for n = 1 and n = 2. Peroxymonosulfuric acid: H 2 SO 5 +6 Peroxomonosulfate, OOSO ...
The first class mostly contains the peroxides of the alkali and alkaline earth metals whereas the covalent peroxides are represented by such compounds as hydrogen peroxide and peroxymonosulfuric acid (H 2 SO 5). In contrast to the purely ionic character of alkali metal peroxides, peroxides of transition metals have a more covalent character. [1]