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A specific example of a M-Z bond wherein other L-ligands are present in the complex [7] Both uncharged transition metal complexes and anionic complexes lead to the required adducts with acidic boranes. On the right is a typical reaction of a Z-ligand where the electron deficit BPh 3 adds to the anionic Fe complex.
An ester of carboxylic acid.R stands for any group (organic or inorganic) and R′ stands for organyl group.. In chemistry, an ester is a compound derived from an acid (organic or inorganic) in which the hydrogen atom (H) of at least one acidic hydroxyl group (−OH) of that acid is replaced by an organyl group (−R).
In the periodic table of the elements, each column is a group. In chemistry, a group (also known as a family) [1] is a column of elements in the periodic table of the chemical elements. There are 18 numbered groups in the periodic table; the 14 f-block columns, between groups 2 and 3, are not numbered.
The conventional symbol Z comes from the German word Zahl 'number', which, before the modern synthesis of ideas from chemistry and physics, merely denoted an element's numerical place in the periodic table, whose order was then approximately, but not completely, consistent with the order of the elements by atomic weights.
A (Z)-group is a group faithfully represented as a doubly transitive permutation group in which no non-identity element fixes more than two points. A (ZT)-group is a (Z)-group that is of odd degree and not a Frobenius group , that is a Zassenhaus group of odd degree, also known as one of the groups PSL(2,2 k +1 ) or Sz(2 2 k +1 ) , for k any ...
The protecting group is abbreviated Cbz or Z (in honor of discoverer Zervas), hence the alternative shorthand designation for benzyl chloroformate as Cbz-Cl or Z-Cl. Benzyloxycarbonyl is a key protecting group for amines , suppressing the nucleophilic and basic properties of the N lone pair .
Dicarbon monoxide is a product of the photolysis of carbon suboxide: [2] [3]. C 3 O 2 → CO + C 2 O. It is stable enough to observe reactions with NO and NO 2. [4]Called ketenylidene in organometallic chemistry, it is a ligand observed in metal carbonyl clusters, e.g. [OC 2 Co 3 (CO) 9] +.
Zinc chemistry resembles that of the late first-row transition metals, nickel and copper, [53] as well as certain main group elements. Almost all zinc compounds have the element in the +2 oxidation state. [54] When Zn 2+ compounds form, the outer shell s electrons are lost, yielding a bare zinc ion with the electronic configuration [Ar]3d 10. [55]