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  2. Hall–Héroult process - Wikipedia

    en.wikipedia.org/wiki/Hall–Héroult_process

    Pure cryolite has a melting point of 1009 ± 1 °C (1848°F). With a small percentage of alumina dissolved in it, its melting point drops to about 1000 °C (1832°F). Besides having a relatively low melting point, cryolite is used as an electrolyte because, among other things, it also dissolves alumina well, conducts electricity, dissociates electrolytically at higher voltage than alumina, and ...

  3. Aluminium smelting - Wikipedia

    en.wikipedia.org/wiki/Aluminium_smelting

    Swelling results in early and non-uniform deterioration of cathode blocks. Anode: Carbon anodes have a specific situation in aluminium smelting and depending on the type of anode, aluminium smelting is divided in two different technologies; “Soderberg” and “prebaked” anodes. Anodes are also made of petroleum coke, mixed with coal-tar ...

  4. Electrometallurgy - Wikipedia

    en.wikipedia.org/wiki/Electrometallurgy

    The electrolysis can be done on a molten metal oxide (smelt electrolysis) which is used for example to produce aluminium from aluminium oxide via the Hall-Hérault process. Electrolysis can be used as a final refining stage in pyrometallurgical metal production (electrorefining) and it is also used for reduction of a metal from an aqueous metal ...

  5. Electrolysis - Wikipedia

    en.wikipedia.org/wiki/Electrolysis

    The reaction at the anode results in chlorine gas from chlorine ions: 2 Cl − → Cl 2 + 2 e −. The reaction at the cathode results in hydrogen gas and hydroxide ions: 2 H 2 O + 2 e − → H 2 + 2 OH −. Without a partition between the electrodes, the OH − ions produced at the cathode are free to diffuse throughout the electrolyte to the ...

  6. Pulse electrolysis - Wikipedia

    en.wikipedia.org/wiki/Pulse_electrolysis

    Pulse electrolysis is an alternate electrolysis method that utilises a pulsed direct current to initiate non-spontaneous chemical reactions. [1] [2] [3] Also known as pulsed direct current (PDC) electrolysis, the increased number of variables that it introduces to the electrolysis method can change the application of the current to the electrodes and the resulting outcome.

  7. Butler–Volmer equation - Wikipedia

    en.wikipedia.org/wiki/Butler–Volmer_equation

    For a simple unimolecular, one-step reaction of the form: O+ne − → R. The forward and backward reaction rates (v f and v b) and, from Faraday's laws of electrolysis, the associated electrical current densities (j), may be written as: = = / = = /

  8. Exchange current density - Wikipedia

    en.wikipedia.org/wiki/Exchange_current_density

    In electrochemistry, exchange current density is a parameter used in the Tafel equation, Butler–Volmer equation and other electrochemical kinetics expressions. The Tafel equation describes the dependence of current for an electrolytic process to overpotential .

  9. Faraday's laws of electrolysis - Wikipedia

    en.wikipedia.org/wiki/Faraday's_laws_of_electrolysis

    Anodization – a process that converts the surface of a metal into a durable corrosion-resistant oxide layer; Conductive polymers – organic polymers that conduct electricity; Water electrolysis – a process that uses an electric current to split water molecules into hydrogen and oxygen gases