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Von Mayer also published a numerical value for mechanical equivalent of heat in 1845 but his experimental method wasn't as convincing. Though a standardised value of 4.1860 J·cal −1 was established in the early 20th century, in the 1920s, it was ultimately realised that the constant is simply the specific heat of water, a quantity that ...
The heating value (or energy value or calorific value) of a substance, usually a fuel or food (see food energy), is the amount of heat released during the combustion of a specified amount of it. The calorific value is the total energy released as heat when a substance undergoes complete combustion with oxygen under standard conditions .
Using these values, Joule was able to determine the mechanical equivalent of heat. Joule estimated a mechanical equivalent of heat to be 819 ft•lbf/Btu (4.41 J/cal). The modern day definitions of heat, work, temperature, and energy all have connection to this experiment. In this arrangement of apparatus, it never happens that the process runs ...
In 1845, Joule published a paper entitled The Mechanical Equivalent of Heat, in which he specified a numerical value for the amount of mechanical work required to "produce a unit of heat", based on heat production by friction in the passage of electricity through a resistor and in the rotation of a paddle in a vat of water. [33]
The British imperial units and U.S. customary units for both energy and work include the foot-pound force (1.3558 J), the British thermal unit (BTU) which has various values in the region of 1055 J, the horsepower-hour (2.6845 MJ), and the gasoline gallon equivalent (about 120 MJ). Log-base-10 of the ratios between various measures of energy
where the quantities are heat-equivalent values. So, for a boiler that produces 210 kW (or 700,000 BTU/h) output for each 300 kW (or 1,000,000 BTU/h) heat-equivalent input, its thermal efficiency is 210/300 = 0.70, or 70%. This means that 30% of the energy is lost to the environment.
That same year, James Prescott Joule suggested to Thomson that the true formula for Carnot's function was [20] = +, where is "the mechanical equivalent of a unit of heat", [21] now referred to as the specific heat capacity of water, approximately 771.8 foot-pounds force per degree Fahrenheit per pound (4,153 J/K/kg). [22]
The above derivation uses the first and second laws of thermodynamics. The first law of thermodynamics is essentially a definition of heat, i.e. heat is the change in the internal energy of a system that is not caused by a change of the external parameters of the system.