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Bromine pentafluoride, Br F 5, is an interhalogen compound and a fluoride of bromine.It is a strong fluorinating agent.. BrF 5 finds use in oxygen isotope analysis. Laser ablation of solid silicates in the presence of BrF 5 releases O 2 for subsequent analysis. [2]
Chemist Linus Pauling first developed the hybridisation theory in 1931 to explain the structure of simple molecules such as methane (CH 4) using atomic orbitals. [2] Pauling pointed out that a carbon atom forms four bonds by using one s and three p orbitals, so that "it might be inferred" that a carbon atom would form three bonds at right angles (using p orbitals) and a fourth weaker bond ...
Chlorine monofluoride (ClF) is the lightest interhalogen compound. ClF is a colorless gas with a normal boiling point of −100 °C. Bromine monofluoride (BrF) has not been obtained as a pure compound — it dissociates into the trifluoride and free bromine. It is created according to the following equation: Br 2 (l) + F 2 (g) → 2 BrF(g)
For some compounds, dynamics occur via dissociation of a ligand, giving a pentacoordinate intermediate, which is subject to the mechanisms discussed above. Yet another mechanism, exhibited by Fe(CO) 4 (SiMe 3 ) 2 and related hydride complexes, is intramolecular scrambling of ligands over the faces of the tetrahedron defined by the four CO ligands.
In particular, Pauling introduced the concept of hybridisation, where atomic s and p orbitals are combined to give hybrid sp, sp 2, and sp 3 orbitals. Hybrid orbitals proved powerful in explaining the molecular geometries of simple molecules like methane, which is tetrahedral with an sp 3 carbon atom and bond angles of 109.5° between the four ...
The octahedron is one of the Platonic solids, although octahedral molecules typically have an atom in their centre and no bonds between the ligand atoms. A perfect octahedron belongs to the point group O h. Examples of octahedral compounds are sulfur hexafluoride SF 6 and molybdenum hexacarbonyl Mo(CO) 6. The term "octahedral" is used somewhat ...
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Isovalent hybridization is used to explain bond angles of those molecules that is inconsistent with the generalized simple sp, sp 2 and sp 3 hybridization. For molecules containing lone pairs, the true hybridization of these molecules depends on the amount of s and p characters of the central atom which is related to its electronegativity.