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Polydimethylsiloxane (PDMS), also known as dimethylpolysiloxane or dimethicone, is a silicone polymer with a wide variety of uses, from cosmetics to industrial lubrication and passive daytime radiative cooling. [1] [2] [3] PDMS is particularly known for its unusual rheological (or flow) properties.
Polydimethylsiloxane is a prevalent siloxane. In organosilicon chemistry, a siloxane is an organic compound containing a functional group of two silicon atoms bound to an oxygen atom: Si−O−Si. The parent siloxanes include the oligomeric and polymeric hydrides with the formulae H[OSiH 2] n OH and [OSiH 2] n. [1]
Polymethylhydrosiloxane (PMHS) is a polymer with the general structure [−CH 3 (H)Si−O−].It is used in organic chemistry as a mild and stable reducing agent easily transferring hydrides to metal centers and a number of other reducible functional groups.
Silicone caulk can be used as a basic sealant against water and air penetration. In organosilicon and polymer chemistry, a silicone or polysiloxane is a polymer composed of repeating units of siloxane (−O−R 2 Si−O−SiR 2 −, where R = organic group).
Trimethylsilanol is a weak acid with a pK a value of 11. [10] The acidity is comparable to that of orthosilicic acid, but much higher than the one of alcohols like tert-butanol (pK a 19 [10]). Deprotonation with sodium hydroxide gives sodium trimethylsiloxide. TMS reacts with the silanol groups (R 3 SiOH) giving silyl ethers.
A cubic silsesquioxane. A silsesquioxane is an organosilicon compound with the chemical formula [RSiO 3/2] n (R = H, alkyl, aryl, alkenyl or alkoxyl.). [1] Silsesquioxanes are colorless solids that adopt cage-like or polymeric structures with Si-O-Si linkages and tetrahedral Si vertices.
PDMS stamps are pieces of polydimethylsiloxane (PDMS), a silicone, that have been patterned usually against a master mold to form a relief pattern used in soft lithography. This PDMS stamp can be used in either its current form as a relief surface for techniques such as microcontact printing or can also be attached to an external source by ...
Silyl-modified polymers (SMP; also silane-modified polymers, modified-silane polymers, MS polymers, silane-terminated polymers, etc.) are polymers terminating with a silyl group. SMPs are the main components in solvent-free and isocyanate-free sealant and adhesive products. [1]