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Soil acidification is the buildup of hydrogen cations, which reduces the soil pH. Chemically, this happens when a proton donor gets added to the soil. The donor can be an acid, such as nitric acid, sulfuric acid, or carbonic acid. It can also be a compound such as aluminium sulfate, which reacts in the soil to release protons.
Water with excess H 3 O + ions is called acid (pH < 7), and water with excess OH – ions is called alkaline or rather basic (pH > 7). Soil moisture with pH < 4 is called very acid and with pH > 10 very alkaline (basic). H 2 CO 3 (carbonic acid) is unstable and produces H 2 O (water) and CO 2 (carbon dioxide gas, escaping into the atmosphere).
The prevailing view in the 1940s and 1950s was that P availability was maximized near neutrality (soil pH 6.5–7.5), and decreased at higher and lower pH. [ 29 ] [ 30 ] Interactions of phosphorus with pH in the moderately to slightly acidic range (pH 5.5–6.5) are, however, far more complex than is suggested by this view.
Some effects of agricultural lime on soil are: it increases the pH of acidic soil, reducing soil acidity and increasing alkalinity [1] it provides a source of calcium for plants; it improves water penetration for acidic soils; it improves the uptake of major plant nutrients (nitrogen, phosphorus, and potassium) of plants growing on acid soils. [2]
The soil's pH also has a strong effect on the amount of volatilization. Specifically, highly alkaline soils (pH~8.2 or higher) have proven to increase urea hydrolysis. One study has shown complete hydrolysis of urea within two days of application on such soils. In acidic soils (pH 5.2) the urea took twice as long to hydrolyze. [7]
Under vacuum, an equilibrium between the content of moisture and air (solved gases) in the liquid and gaseous phase is achieved. The equilibrium depends on the temperature and the residual pressure. The lower that pressure, the faster and more efficiently are water and gas removed.
The lower the pH, the higher the concentration of bicarbonate will be. This shows how a lower pH can lead to higher alkalinity if the amount of bicarbonate produced is greater than the amount of H + remaining after the reaction. This is the case since the amount of acid in the rainwater is low.
Deep soil mixing requires specialized auger mixing equipment. In order to apply this method in-situ and in deep soil, the oxidant must be pumped to the point of mixing using a kelly bar (a piece of earth drilling equipment), or appropriate piping to the place where the soil needs to be oxidized. The soil then has to be mixed by using mixing blades.
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