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Carbon dioxide is often mentioned in the context of its increased influence as a greenhouse gas since the pre-industrial (1750) era. In 2013, the increase in CO 2 was estimated to be responsible for 1.82 W m −2 of the 2.63 W m −2 change in radiative forcing on Earth (about 70%). [48]
The gas constant R is defined as the Avogadro constant N A multiplied by the Boltzmann constant k (or k B): = = 6.022 140 76 × 10 23 mol −1 × 1.380 649 × 10 −23 J⋅K −1 = 8.314 462 618 153 24 J⋅K −1 ⋅mol −1. Since the 2019 revision of the SI, both N A and k are defined with exact numerical values when expressed in SI units. [2]
By mole fraction (i.e., by quantity of molecules), dry air contains 78.08% nitrogen, 20.95% oxygen, 0.93% argon, 0.04% carbon dioxide, and small amounts of other trace gases (see Composition below for more detail). Air also contains a variable amount of water vapor, on average around 1% at sea level, and 0.4% over the entire atmosphere.
Carbon dioxide liquid/vapor equilibrium thermodynamic data: Temp. °C P vap Vapor pressure kPa H liq Heat content liquid J/g H vap Heat content vapor J/g
= milligrams of pollutant per cubic meter of air at sea level atmospheric pressure and T: ppmv = air pollutant concentration, in parts per million by volume T = ambient temperature in K = 273. + °C 0.082057338 = Universal gas constant in L atm mol −1 K −1: M = molecular mass (or molecular weight) of the air pollutant
= air pollutant concentration, in parts per million by volume mg/m 3 = milligrams of pollutant per cubic meter of air = atmospheric temperature in kelvins = 273.15 + °C 0.08205 = Universal Gas Law constant in atm·l/(mol·K) = molecular weight of the air pollutant (dimensionless)
The standards below are two examples of commonly used and cited publications that provide a composition for standard dry air: ISO TR 29922-2017 provides a definition for standard dry air which specifies an air molar mass of 28,965 46 ± 0,000 17 kg·kmol-1. [2] GPA 2145:2009 is published by the Gas Processors Association.
Atmospheric carbon dioxide (CO 2) concentrations from 1958 to 2023. The Keeling Curve is a graph of the annual variation and overall accumulation of carbon dioxide in the Earth's atmosphere based on continuous measurements taken at the Mauna Loa Observatory on the island of Hawaii from 1958 to the present day.