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The Grieco elimination is an organic reaction describing the elimination reaction of an aliphatic primary alcohol through a selenide to a terminal alkene. [ 1 ] [ 2 ] It is named for Paul Grieco . The alcohol first reacts with o -nitrophenylselenocyanate and tributylphosphine to form a selenide via a nucleophilic substitution on the electron ...
The Chugaev elimination is a chemical reaction that involves the elimination of water from alcohols to produce alkenes. The intermediate is a xanthate . It is named for its discoverer, the Russian chemist Lev Aleksandrovich Chugaev (1873–1922), who first reported the reaction sequence in 1899.
In organic chemistry, the E i mechanism (Elimination Internal/Intramolecular), also known as a thermal syn elimination or a pericyclic syn elimination, is a special type of elimination reaction in which two vicinal (adjacent) substituents on an alkane framework leave simultaneously via a cyclic transition state to form an alkene in a syn elimination. [1]
Selenoxide elimination (also called α-selenation) [1] is a method for the chemical synthesis of alkenes from selenoxides. It is most commonly used to synthesize α,β-unsaturated carbonyl compounds from the corresponding saturated analogues. [2] It is mechanistically related to the Cope reaction.
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Data in a RAW-file is structured according to the Bayer filter's pattern in cameras that use a single image sensor. Debayering, the process of obtaining bitmap data from a RAW-image is always a lossy operation. [citation needed] In addition, some downsampling is always performed, again reducing image information.
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