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Hydrogen sulfide is a chemical compound with the formula H 2 S.It is a colorless chalcogen-hydride gas, and is toxic, corrosive, and flammable, with trace amounts in ambient atmosphere having a characteristic foul odor of rotten eggs. [11]
Causes: Sulfur medications such as phenacetin, metoclopramide, dapsone, phenzopyridine, and trimethoprim-sulfamethoxazole; hydrogen-sulfide-producing intestinal bacteria, such as Morganella morganii: Risk factors: Pulmonary arteriovenous malformation: Prevention: Avoidance of sulfur-containing compounds including drugs: Treatment: Blood ...
Hydrogen sulfide is also a potent cellular toxin, blocking the cytochrome system and inhibiting cellular respiration. More water-soluble gases (e.g. chlorine, ammonia, sulfur dioxide, hydrogen chloride) dissolve in the upper airway and immediately cause mucous membrane irritation, which may alert people to the need to escape the exposure.
Many gases have toxic properties, which are often assessed using the LC 50 (median lethal concentration) measure. In the United States, many of these gases have been assigned an NFPA 704 health rating of 4 (may be fatal) or 3 (may cause serious or permanent injury), and/or exposure limits (TLV, TWA/PEL, STEL, or REL) determined by the ACGIH professional association.
One of these chemical reactions involves hydrogen sulfide (H 2 S) in sulfide stress cracking (SSC), a significant problem for the oil and gas industries. [32] After a manufacturing process or treatment which may cause hydrogen ingress, the component should be baked to remove or immobilize the hydrogen. [29]
Prolonged low-level exposure may cause fatigue, pneumonia, loss of appetite, headaches, irritability, poor memory, and dizziness. High concentrations of hydrogen sulfide (>150 ppm) can produce olfactory fatigue, whereby the scent becomes undetectable. At higher concentrations (>300 ppm), hydrogen sulfide can cause loss of consciousness and death.
An example of histotoxic hypoxia is cyanide poisoning. There is a profound drop in tissue oxygen consumption since the reaction of oxygen with cytochrome oxidase is blocked by the presence of cyanide. Cyanide binds to the ferric ion on cytochrome oxidase a 3 and prevents the fourth and final reaction in the electron transport chain.
To reduce the extra sulfur in the ruminant's diet, ruminal bacteria break the excess down, resulting in Hydrogen Sulfide, which is soluble in water, but as temperature increases, the solubility decreases, which leads to the hydrogen sulfide gas being reinhaled by the animal, causing sulfur induced polioencephalomalacia.
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