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The ideal gas equation can be rearranged to give an expression for the molar volume of an ideal gas: = = Hence, for a given temperature and pressure, the molar volume is the same for all ideal gases and is based on the gas constant: R = 8.314 462 618 153 24 m 3 ⋅Pa⋅K −1 ⋅mol −1, or about 8.205 736 608 095 96 × 10 −5 m 3 ⋅atm⋅K ...
Gas solubility coefficients are used to calculate Henry's law constant: x g = p g / H {\displaystyle x_{g}=p_{g}/H} After manipulating equations and substituting volumes of each phase, the molar concentration of water (55.5 mol/L) and the molecular weight of the gas analyte (MW), a final equation is solved:
Gay-Lussac used the formula acquired from ΔV/V = αΔT to define the rate of expansion α for gases. For air, he found a relative expansion ΔV/V = 37.50% and obtained a value of α = 37.50%/100 °C = 1/266.66 °C which indicated that the value of absolute zero was approximately 266.66 °C below 0 °C. [ 12 ]
where P is the pressure, V is volume, n is the number of moles, R is the universal gas constant and T is the absolute temperature. The proportionality constant, now named R, is the universal gas constant with a value of 8.3144598 (kPa∙L)/(mol∙K). An equivalent formulation of this law is: =
For a given mass of an ideal gas, the volume and amount (moles) of the gas are directly proportional if the temperature and pressure are constant. The law is named after Amedeo Avogadro who, in 1812, [ 2 ] [ 3 ] hypothesized that two given samples of an ideal gas, of the same volume and at the same temperature and pressure, contain the same ...
For his work with gases a century prior, the physical constant that bears his name (the Avogadro constant) is the number of atoms per mole of elemental carbon-12 (6.022 × 10 23 mol −1). This specific number of gas particles, at standard temperature and pressure (ideal gas law) occupies 22.40 liters, which is referred to as the molar volume.
Any extensive quantity E for a sample can be divided by the sample's volume, to become the "E density" for the sample; similarly, any extensive quantity "E" can be divided by the sample's mass, to become the sample's "specific E"; extensive quantities "E" which have been divided by the number of moles in their sample are referred to as "molar E".
Volume percent is the concentration of a certain solute, measured by volume, in a solution.It has as a denominator the volume of the mixture itself, as usual for expressions of concentration, [2] rather than the total of all the individual components’ volumes prior to mixing: