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It is far less reactive than the other nitrogen trihalides nitrogen trichloride, nitrogen tribromide, and nitrogen triiodide, all of which are explosive. Alone among the nitrogen trihalides it has a negative enthalpy of formation. It is prepared in modern times both by direct reaction of ammonia and fluorine and by a variation of Ruff's method. [6]
Cyanogen fluoride (molecular formula: FCN; IUPAC name: carbononitridic fluoride) is an inorganic linear compound which consists of a fluorine atom in a single bond with a carbon atom, and a nitrogen atom in a triple bond with the carbon atom. It is a toxic and explosive gas at room temperature.
Cyanogen is typically generated from cyanide compounds. One laboratory method entails thermal decomposition of mercuric cyanide: . 2 Hg(CN) 2 → (CN) 2 + Hg 2 (CN) 2 Or, one can combine solutions of copper(II) salts (such as copper(II) sulfate) with cyanides; an unstable copper(II) cyanide is formed which rapidly decomposes into copper(I) cyanide and cyanogen.
In chemistry, cyanide (from Greek kyanos ' dark blue ') is a chemical compound that contains a C≡N functional group. This group, known as the cyano group , consists of a carbon atom triple-bonded to a nitrogen atom.
Trifluorides are compounds in which one atom or ion has three fluorine atoms or ions associated. Many metals form trifluorides, such as iron, the rare-earth elements, and the metals in the groups 3, 13 and 15 of the periodic table.
nitrogen trifluoride: 7783-54-2 F 3 NO: nitrogen trifluoride oxide: 13847-65-9 F 3 NO 2 S: difluoroaminosulfonyl fluoride: 13709-30-3 F 3 NO 3 S: difluoraminooxysulfonyl fluoride: 6816-12-2 F 3 NS: thiazyl trifluoride: 15930-75-3 F 3 NaSn: sodium trifluorostannate: 13782-22-4 F 3 Nd: neodymium trifluoride: 13709-42-7 F 3 OP: phosphoryl fluoride ...
Nitrogen fluorides are compounds of chemical elements nitrogen and fluorine. Many different nitrogen fluorides are known: ... Nitrogen trifluoride, NF 3; Nitrogen ...
Trifluoramine oxide was first discovered in 1966 independently by two different groups. One way to produce it was by an electric discharge in a mixture of oxygen on nitrogen trifluoride. Another even less yielding method is by reacting noble metal fluorides (IrF 6 or PtF 6) with nitric oxide. [1]