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1-Methylcyclohexene is used as a probe of the stereochemistry of reactions involving alkenes because it is prochiral and the two sp 2-carbon atoms differ. "Hydrosilylation of Cyclohexene"
Methylcyclohexanones are a group of three isomers: 2-methylcyclohexanone, 3-methylcyclohexanone, and 4-methylcyclohexanone. [1] They can be viewed as derivative of cyclohexanone. They can be prepared by oxidation of methylcyclohexane as well as partial hydrogenation of the corresponding cresols. All are colorless liquids.
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Synthesis. 3-Methylcyclohexene is produced from 3-methylcyclohexanone. [1] References This page was last edited on 2 November 2024, at 01 ...
4-Methylcyclohexene is an organic compound consisting of cyclohexene with a methyl group substituent attached to carbon most distant from the alkene group. Two other structural isomers are known: 1-methylcyclohexene and 3-methylcyclohexene.
Initial synthesis gave a racemic form of the compound using an intramolecular etherification reaction of the alcohol motifs and the double bond. Yamamoto and coworkers report the use of an alternative intramolecular Robinson annulation to provide a straightforward enantioselective synthesis of tetracyclic core of platensimycin.
Synthesis. It can be produced by a Wittig reaction or a reaction with a Tebbe's reagent from cyclohexanone. [1] [2] [3] It can also be synthesized as a side product ...
Cyclohexenone is also used in multi-step synthesis in the construction of polycyclic natural products. It is prochiral. With strong bases, the positions 4 and 6 (the two CH 2-groups of the carbonyl group and the C-C double bond adjacent) are deprotonated. Cyclohexenone is an in-vitro catalyst for a relatively mild decarboxylation of alpha amino ...