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A polarimeter [1] is a scientific instrument used to measure optical rotation: the angle of rotation caused by passing linearly polarized light through an optically active substance. [ 2 ] Some chemical substances are optically active, and linearly polarized (uni-directional) light will rotate either to the left (counter-clockwise) or right ...
Optical rotation, also known as polarization rotation or circular birefringence, is the rotation of the orientation of the plane of polarization about the optical axis of linearly polarized light as it travels through certain materials.
Recording optical rotation with a polarimeter: The plane of polarisation of plane polarised light (4) rotates (6) as it passes through an optically active sample (5). This angle is determined with a rotatable polarizing filter (7). In chemistry, specific rotation ([α]) is a property of a chiral chemical compound.
A simple polarimeter to measure this rotation consists of a long tube with flat glass ends, into which the sample is placed. At each end of the tube is a Nicol prism or other polarizer. Light is shone through the tube, and the prism at the other end, attached to an eye-piece, is rotated to arrive at the region of complete brightness or that of ...
[citation needed] This dependence of specific rotation on wavelength is called optical rotatory dispersion. In all materials the rotation varies with wavelength. The variation is caused by two quite different phenomena. The first accounts in most cases for the majority of the variation in rotation and should not strictly be termed rotatory ...
For rotation from the laboratory frame to the local frame, the sign of the sine terms inverts. Linear polarizer (horizontal transmission) The Mueller matrices for other polarizer rotation angles can be generated by reference frame rotation.
The observed rotation of the sample is the weighted sum of the optical rotation of each anomer weighted by the amount of that anomer present. Therefore, one can use a polarimeter to measure the rotation of a sample and then calculate the ratio of the two anomers present from the enantiomeric excess, as long as one knows the rotation of each pure anomer.
The Stokes I, Q, U and V parameters. The Stokes parameters are a set of values that describe the polarization state of electromagnetic radiation.They were defined by George Gabriel Stokes in 1851, [1] [2] as a mathematically convenient alternative to the more common description of incoherent or partially polarized radiation in terms of its total intensity (I), (fractional) degree of ...
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