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Sodium hypophosphite (NaPO 2 H 2, also known as sodium phosphinate) is the sodium salt of hypophosphorous acid and is often encountered as the monohydrate, NaPO 2 H 2 ·H 2 O. It is a solid at room temperature, appearing as odorless white crystals. It is soluble in water, and easily absorbs moisture from the air.
An amphiprotic molecule (or ion) can either donate or accept a proton, thus acting either as an acid or a base. Water, amino acids, hydrogencarbonate ion (or bicarbonate ion) HCO − 3, dihydrogen phosphate ion H 2 PO − 4, and hydrogensulfate ion (or bisulfate ion) HSO − 4 are common examples of amphiprotic species. Since they can donate a ...
The salt is obtained by partial neutralization of phosphoric acid. The pK a of monosodium phosphate is 6.8-7.2 (depending on the physicochemical characteristics during pK a determination). [2] Heating this salt above 169 °C gives disodium pyrophosphate: 2 NaH 2 PO 4 → Na 2 H 2 P 2 O 7 + H 2 O. When heated at 550 °C, anhydrous trisodium ...
This means that salts of the mono- and di-phosphate ions can be selectively crystallised from aqueous solution by setting the pH value to either 4.7 or 9.8. In effect, H 3 PO 4, H 2 (PO 4) − and H(PO 4) 2− behave as separate weak acids because the successive pK a differ by more than 4. Phosphate can form many polymeric ions such as ...
A sodium phosphate is a generic variety of salts of sodium (Na +) and phosphate (PO 3− 4). Phosphate also forms families or condensed anions including di-, tri-, tetra-, and polyphosphates. Most of these salts are known in both anhydrous (water-free) and hydrated forms. The hydrates are more common than the anhydrous forms. [1]
A typical derivative is the salt [NH 4][HP(O) 2 OH]. [7] [6] Many related salts are known, e.g., RbHPHO 3, CsHPHO 3, TlHPHO 3. These salts are prepared by treating phosphorous acid with the metal carbonate. These compounds contain a layer polymeric anion consisting of HPO 3 tetrahedra linked by hydrogen bonds. These layers are interleaved by ...
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
HPA is usually supplied as a 50% aqueous solution and heating at low temperatures (up to about 90 °C) prompts it to react with water to form phosphorous acid and hydrogen gas. H 3 PO 2 + H 2 O → H 3 PO 3 + H 2. Heating above 110 °C causes hypophosphorous acid to undergo disproportionation to give phosphorous acid and phosphine. [7] 3 H 3 PO ...