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The reaction of an organic substrate with phosgene is called phosgenation. [9] Phosgenation of diols give carbonates (R = H, alkyl, aryl), which can be either linear or cyclic: n HO−CR 2 −X−CR 2 −OH + n COCl 2 → [−O−CR 2 −X−CR 2 −O−C(=O)−] n + 2n HCl. An example is the reaction of phosgene with bisphenol A to form ...
Phosgene oxime can be prepared by reduction of chloropicrin using a combination of tin metal and hydrochloric acid as the source of the active hydrogen reducing agent: Cl 3 CNO 2 + 4 [H] → Cl 2 C=N−OH + HCl + H 2 O. The observation of a transient violet color in the reaction suggests intermediate formation of trichloronitrosomethane (Cl 3 ...
The main polycarbonate material is produced by the reaction of bisphenol A (BPA) and phosgene COCl 2. The overall reaction can be written as follows: The first step of the synthesis involves treatment of bisphenol A with sodium hydroxide, which deprotonates the hydroxyl groups of the bisphenol A. [6] (HOC 6 H 4) 2 CMe 2 + 2 NaOH → Na 2 (OC 6 ...
The ion-permeable ion-exchange membrane at the center of the cell allows only the sodium ions (Na +) to pass to the second chamber where they react with the hydroxide ions to produce caustic soda (NaOH) (B in figure): [1] Na + + OH − → NaOH The overall reaction for the electrolysis of brine is thus: 2NaCl + 2 H 2 O → Cl 2 + H 2 + 2NaOH
An element–reaction–product table is used to find coefficients while balancing an equation representing a chemical reaction. Coefficients represent moles of a substance so that the number of atoms produced is equal to the number of atoms being reacted with. [1] This is the common setup: Element: all the elements that are in the reaction ...
A chemical equation is the symbolic representation of a chemical reaction in the form of symbols and chemical formulas.The reactant entities are given on the left-hand side and the product entities are on the right-hand side with a plus sign between the entities in both the reactants and the products, and an arrow that points towards the products to show the direction of the reaction. [1]
Diphosgene is an organic chemical compound with the formula ClCO 2 CCl 3. This colorless liquid is a valuable reagent in the synthesis of organic compounds . Diphosgene is related to phosgene and has comparable toxicity , but is more conveniently handled because it is a liquid, whereas phosgene is a gas.
The Vilsmeier–Haack reaction (also called the Vilsmeier reaction) is the chemical reaction of a substituted formamide (1) with phosphorus oxychloride and an electron-rich arene (3) to produce an aryl aldehyde or ketone (5): RC(=O)NR ′ R″ + HArZ + POCl 3 + H 2 O → RC(=O)ArZ + NR ′ R″H + HCl + H 3 PO 4