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3-Methylhexane is a branched hydrocarbon with two enantiomers. [2] It is one of the isomers of heptane. The molecule is chiral, and is one of the two isomers of heptane to have this property, the other being its structural isomer 2,3-dimethylpentane. The enantiomers are (R)-3-methylhexane [3] and (S)-3-methylhexane. [4]
Phase-field models are usually constructed in order to reproduce a given interfacial dynamics. For instance, in solidification problems the front dynamics is given by a diffusion equation for either concentration or temperature in the bulk and some boundary conditions at the interface (a local equilibrium condition and a conservation law), [14] which constitutes the sharp interface model.
In addition to infinite dilution, MOSCED can be used to parameterize excess Gibbs Free Energy model such as NRTL, WILSON, Mod-UNIFAC to map out Vapor Liquid Equilibria of mixture. This was demonstrated briefly by Schriber and Eckert [ 3 ] using infinite dilution data to parameterize WILSON equation.
Apart from modelling melting of solids, Stefan problem is also used as a model for the asymptotic behaviour (in time) of more complex problems. For example, Pego [10] uses matched asymptotic expansions to prove that Cahn-Hilliard solutions for phase separation problems behave as solutions to a non-linear Stefan problem at an intermediate time ...
By reaction with tertiary amines, long-chain alkyl bromides such as 1-bromododecane, give quaternary ammonium salts, which are used as phase transfer catalysts. [9] With Michael acceptors the addition is also anti-Markovnikov because now a nucleophilic X − reacts in a nucleophilic conjugate addition for example in the reaction of HCl with ...
In organic chemistry, free-radical halogenation is a type of halogenation. This chemical reaction is typical of alkanes and alkyl-substituted aromatics under application of UV light. The reaction is used for the industrial synthesis of chloroform (CHCl 3), dichloromethane (CH 2 Cl 2), and hexachlorobutadiene. It proceeds by a free-radical chain ...
C 3 H 5-Cl + NaF → R-F + NaCl This kind of reaction is called Finkelstein reaction . [ 2 ] However, it is also possible, for example, to produce phosphorus fluoride compounds by transhalogenating chlorine, bromine or iodine bound to phosphorus with a metal fluoride.
It is written in C++, while the BUGS family is written in Component Pascal, a less widely known programming language. [6] [7] In addition, JAGS is already part of many repositories of Linux distributions such as Ubuntu. It can also be compiled as a 64-bit application on 64-bit platforms, thus making all the addressable space available to BUGS ...