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If the volumetric expansion coefficient does change appreciably with temperature, or the increase in volume is significant, then the above equation will have to be integrated: (+) = = (()) where () is the volumetric expansion coefficient as a function of temperature T, and and are the initial and final temperatures respectively.
where γ is the heat capacity ratio, α is the volumetric coefficient of thermal expansion, ρ = N/V is the particle density, and = (/) is the thermal pressure coefficient. In an extensive thermodynamic system, the application of statistical mechanics shows that the isothermal compressibility is also related to the relative size of fluctuations ...
The laws of thermodynamics imply the following relations between these two heat capacities (Gaskell 2003:23): = = Here is the thermal expansion coefficient: = is the isothermal compressibility (the inverse of the bulk modulus):
Some formulations for the Grüneisen parameter include: = = = = = ( ) where V is volume, and are the principal (i.e. per-mass) heat capacities at constant pressure and volume, E is energy, S is entropy, α is the volume thermal expansion coefficient, and are the adiabatic and isothermal bulk moduli, is the speed of sound in the medium ...
To distinguish these two thermal expansion equations of state, the latter one is called pressure-dependent thermal expansion equation of state. To deveop the pressure-dependent thermal expansion equation of state, in an compression process at room temperature from (V 0, T 0, P 0) to (V 1, T 0,P 1), a general form of volume is expressed as
As quoted from this source in an online version of: J.A. Dean (ed), Lange's Handbook of Chemistry (15th Edition), McGraw-Hill, 1999; Section 4; Table 4.1, Electronic Configuration and Properties of the Elements Touloukian, Y. S., Thermophysical Properties of Matter, Vol. 12, Thermal Expansion, Plenum, New York, 1975.
In thermodynamics, the Volume Correction Factor (VCF), also known as Correction for the effect of Temperature on Liquid (CTL), is a standardized computed factor used to correct for the thermal expansion of fluids, primarily, liquid hydrocarbons at various temperatures and densities. [1]
In crystallography, materials science and metallurgy, Vegard's law is an empirical finding (heuristic approach) resembling the rule of mixtures.In 1921, Lars Vegard discovered that the lattice parameter of a solid solution of two constituents is approximately a weighted mean of the two constituents' lattice parameters at the same temperature: [1] [2]