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Sodium ferrocyanide is the sodium salt of the coordination compound of formula [Fe(CN) 6] 4−. In its hydrous form, Na 4 Fe(CN) 6 · H 2 O (sodium ferrocyanide decahydrate), it is sometimes known as yellow prussiate of soda. It is a yellow crystalline solid that is soluble in water and insoluble in alcohol. The yellow color is the color of ...
+4 +6 +8 8 [136] 109 meitnerium: Mt +1 +3 +6 9 [136] 110 darmstadtium: Ds +2 +4 +6 10 [136] 111 roentgenium: Rg −1 +3 +5 11 [136] 112 copernicium: Cn +2 +4 12 [136] 113 nihonium: Nh 13 114 flerovium: Fl 14 115 moscovium: Mc 15 116 livermorium: Lv −2 +4 16 [137] 117 tennessine: Ts −1 +5 17 118 oganesson: Og −1 +1 +2 +4 +6 18 [136] [138 ...
Ferrocyanide is the name of the anion [Fe 6] 4−. Salts of this coordination complex give yellow solutions. It is usually available as the salt potassium ferrocyanide, which has the formula K 4 Fe(CN) 6. [Fe(CN) 6] 4− is a diamagnetic species, featuring low-spin iron(II) center in an octahedral ligand environment.
For example, Cu compounds with Cu oxidation state +2 are called cupric and those with state +1 are cuprous. [4]: 172 The oxidation numbers of elements allow predictions of chemical formula and reactions, especially oxidation-reduction reactions. The oxidation numbers of the most stable chemical compounds follow trends in the periodic table.
In these cases the oxidation number (the same as the charge) of the metal ion is represented by a Roman numeral in parentheses immediately following the metal ion name. For example, in uranium(VI) fluoride the oxidation number of uranium is 6. Another example is the iron oxides. FeO is iron(II) oxide and Fe 2 O 3 is iron(III) oxide.
By far the largest application of cyanometalates is the production of [Au(CN) 2] − in the extraction of gold from low grade ores. This conversion involves oxidation of metallic gold into Au + : 4 Au + 8 CN − + O 2 + 2 H 2 O → 4 [Au(CN) 2 ] − + 4 OH −
Prussian blue (also known as Berlin blue, Brandenburg blue, Parisian and Paris blue) is a dark blue pigment produced by oxidation of ferrous ferrocyanide salts. It has the chemical formula Fe 3+ 4 [Fe 2+ 6] 3.
For example, if the manganese in [HMnO 4] − has an oxidation state of +6 and nE° = 4, and in MnO 2 the oxidation state is +4 and nE° = 0, then the slope Δy/Δx is 4/2 = 2, yielding a standard potential of +2. The stability of any terms can be similarly found by this graph.
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