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It is the same concept as volume percent (vol%) except that the latter is expressed with a denominator of 100, e.g., 18%. The volume fraction coincides with the volume concentration in ideal solutions where the volumes of the constituents are additive (the volume of the solution is equal to the sum of the volumes of its ingredients).
When expressed in percent, it is known as the mole percent or molar percentage (unit symbol %, sometimes "mol%", equivalent to cmol/mol for 10 −2). The mole fraction is called amount fraction by the International Union of Pure and Applied Chemistry (IUPAC) [ 1 ] and amount-of-substance fraction by the U.S. National Institute of Standards and ...
For example, the conversion factor between a mass fraction of 1 ppb and a mole fraction of 1 ppb is about 4.7 for the greenhouse gas CFC-11 in air (Molar mass of CFC-11 / Mean molar mass of air = 137.368 / 28.97 = 4.74). For volume fraction, the suffix "V" or "v" is sometimes appended to the parts-per notation (e.g. ppmV, ppbv, pptv).
The ideal gas equation can be rearranged to give an expression for the molar volume of an ideal gas: = = Hence, for a given temperature and pressure, the molar volume is the same for all ideal gases and is based on the gas constant: R = 8.314 462 618 153 24 m 3 ⋅Pa⋅K −1 ⋅mol −1, or about 8.205 736 608 095 96 × 10 −5 m 3 ⋅atm⋅K ...
For a given mass of an ideal gas, the volume and amount (moles) of the gas are directly proportional if the temperature and pressure are constant. The law is named after Amedeo Avogadro who, in 1812, [ 2 ] [ 3 ] hypothesized that two given samples of an ideal gas, of the same volume and at the same temperature and pressure, contain the same ...
Another example of the apparent molar volume of the second component is less than its molar volume as a pure substance is the case of ethanol in water. For example, at 20 mass percents ethanol, the solution has a volume of 1.0326 liters per kg at 20 °C, while pure water is 1.0018 L/kg (1.0018 cc/g). [ 5 ]
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