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Thiosulfate (IUPAC-recommended spelling; sometimes thiosulphate in British English) is an oxyanion of sulfur with the chemical formula S 2 O 2− 3.Thiosulfate also refers to the compounds containing this anion, which are the salts of thiosulfuric acid, such as sodium thiosulfate Na 2 S 2 O 3 and ammonium thiosulfate (NH 4) 2 S 2 O 3.
Alkylation of sodium thiosulfate gives S-alkylthiosulfates, which are called Bunte salts. [16] The alkylthiosulfates are susceptible to hydrolysis, affording the thiol. This reaction is illustrated by one synthesis of thioglycolic acid: ClCH 2 CO 2 H + Na 2 S 2 O 3 → Na[O 3 S 2 CH 2 CO 2 H] + NaCl Na[O 3 S 2 CH 2 CO 2 H] + H 2 O → HSCH 2 CO ...
Also acid ionization constant or acidity constant. A quantitative measure of the strength of an acid in solution expressed as an equilibrium constant for a chemical dissociation reaction in the context of acid-base reactions. It is often given as its base-10 cologarithm, p K a. acid–base extraction A chemical reaction in which chemical species are separated from other acids and bases. acid ...
Sodium persulfate is a specialized oxidizing agent in chemistry, classically in the Elbs persulfate oxidation and the Boyland–Sims oxidation reactions. It is also used in radical reactions; for example in a synthesis of diapocynin from apocynin where iron(II) sulfate is the radical initiator. [7]
Iodometry, known as iodometric titration, is a method of volumetric chemical analysis, a redox titration where the appearance or disappearance of elementary iodine indicates the end point. Note that iodometry involves indirect titration of iodine liberated by reaction with the analyte, whereas iodimetry involves direct titration using iodine as ...
The Gibbs free energy change for (for example) the dithionate anion's oxidation to sulfate is a negative −300 kJ/mol, making it thermodynamically unstable against oxidation, but the kinetics for this reaction are rather poor. For similar reasons, the dithionate anion has been used to form single crystals of large cation complexes in high ...
Sodium sulfite (sodium sulphite) is the inorganic compound with the chemical formula Na 2 SO 3. A white, water-soluble solid, it is used commercially as an antioxidant and preservative. It is also suitable for the softening of lignin in the pulping and refining processes of wood and lignocellulosic materials. [1]
The iodine clock reaction is a classical chemical clock demonstration experiment to display chemical kinetics in action; it was discovered by Hans Heinrich Landolt in 1886. [1] The iodine clock reaction exists in several variations, which each involve iodine species (iodide ion, free iodine, or iodate ion) and redox reagents in the presence of ...