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The solubility of tantalum pentachloride increases slightly for the following series of aromatic hydrocarbons: benzene < toluene < m-xylene < mesitylene. This is reflected in the deepening of colour of the solutions from pale yellow to orange. Tantalum pentachloride is less soluble in cyclohexane and carbon tetrachloride than in the aromatic ...
The tables below provides information on the variation of solubility of different substances (mostly inorganic compounds) in water with temperature, at one atmosphere pressure. Units of solubility are given in grams of substance per 100 millilitres of water (g/100 ml), unless shown otherwise. The substances are listed in alphabetical order.
Tantalum(III) chloride is formed by reducing tantalum(V) chloride with tantalum metal. this is done by heating tantalum(III) chloride to 305 °C, passing the vapour over tantalum foil at 600°, and condensing the trichloride at 365 °C. If the condensing region is kept at too high a temperature, then TaCl 2.5 deposits instead. [5]
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
When tantalum enrichment is observed, it is probably due to loss of more water-soluble elements in aerosols in the clouds. [87] Pollution linked to human use of the element has not been detected. [88] Tantalum appears to be a very conservative element in biogeochemical terms, but its cycling and reactivity are still not fully understood.
Trimethylphosphine was introduced by vapour transfer to dichlorotrimethyltantalum frozen in a liquid nitrogen bath, resulting in the seven-coordinate bisphosphine complex. The complex, like 2,2'-Bipyridyldichloro(trimethyl)-tantalum(V), resembles a capped trigonal prism, but with a trimethylphosphine ligand capping instead of a chloride.
Tantalum alkylidene complexes arise by treating trialkyltantalum dichloride with alkyl lithium reagents. This reaction initially forms a thermally unstable tetraalkyl-monochloro-tantalum complex, which undergoes α-hydrogen elimination, followed by alkylation of the remaining chloride.
This page contains tables of azeotrope data for various binary and ternary mixtures of solvents. The data include the composition of a mixture by weight (in binary azeotropes, when only one fraction is given, it is the fraction of the second component), the boiling point (b.p.) of a component, the boiling point of a mixture, and the specific gravity of the mixture.