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In chemistry, polarity is a separation of electric charge leading to a molecule or its chemical groups having an electric dipole moment, with a negatively charged end and a positively charged end. Polar molecules must contain one or more polar bonds due to a difference in electronegativity between the bonded atoms.
In electrochemistry, polarization is a collective term for certain mechanical side-effects (of an electrochemical process) by which isolating barriers develop at the interface between electrode and electrolyte. These side-effects influence the reaction mechanisms, as well as the chemical kinetics of corrosion and metal deposition.
The polarization is proportional to the macroscopic field by = = where is the electric permittivity constant and is the electric susceptibility. Using this proportionality, we find the local field as F = 1 3 ( ε r + 2 ) E {\displaystyle \mathbf {F} ={\tfrac {1}{3}}(\varepsilon _{\mathrm {r} }+2)\mathbf {E} } which can be used in the definition ...
Polarization (antenna), the state of polarization (in the above sense) of electromagnetic waves transmitted by or received by a radio antenna; Dielectric polarization, charge separation in insulating materials: Polarization density, volume dielectric polarization; Dipolar polarization, orientation of permanent dipoles
The polarization of a molecule through its bonds is a separate phenomenon known as induction. [3] Field effects are relatively weak, and diminish rapidly with distance, but have still been found to alter molecular properties such as acidity. [1] Field effect on a carbonyl arising from the dipole in a C-F bond.
In inorganic chemistry, Fajans' rules, formulated by Kazimierz Fajans in 1923, [1] [2] [3] are used to predict whether a chemical bond will be covalent or ionic, and depend on the charge on the cation and the relative sizes of the cation and anion. They can be summarized in the following table:
Concentration polarization is a term used in the scientific fields of electrochemistry and membrane science. In electrochemistry. In electrochemistry, ...
Polarization is observed in the light of the sky, as this is due to sunlight scattered by aerosols as it passes through Earth's atmosphere. The scattered light produces the brightness and color in clear skies. This partial polarization of scattered light can be used to darken the sky in photographs, increasing the contrast.