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If an anionic surfactant is present, then the cationic methylene blue and the anionic surfactant forms an ion pair, which is extracted into the organic phase. The color saturation of the chloroform increases with the concentration of anionic surfactants. MBAS assay is an ASTM International standard technique for detecting anionic surfactants. [3]
Surfactant molecules have either one tail or two; those with two tails are said to be double-chained. [4] Surfactant classification according to the composition of their head: non-ionic, anionic, cationic, amphoteric. Most commonly, surfactants are classified according to polar head group. A non-ionic surfactant has no charged groups in its ...
Bottle of 20% sodium dodecyl sulfate in distilled water for use in the laboratory. The critical micelle concentration (CMC) in water at 25 °C is 8.2 mM, [1] and the aggregation number at this concentration is usually considered to be about 62. [3] The micelle ionization fraction (α) is around 0.3 (or 30%). [4]
Benzalkonium chloride (BZK, BKC, BAK, BAC), also known as alkyldimethylbenzylammonium chloride (ADBAC) and by the trade name Zephiran, [1] is a type of cationic surfactant. It is an organic salt classified as a quaternary ammonium compound. ADBACs have three main categories of use: as a biocide, a cationic surfactant, and a phase transfer agent ...
Upon introducing surfactants (or any surface active materials) into a system, they will initially partition into the interface, reducing the system free energy by: [citation needed] lowering the energy of the interface (calculated as area times surface tension), and; removing the hydrophobic parts of the surfactant from contact with water.
[1] [2] The cationic surfactant concentration in conditioners is generally of the order of 1–2% and the alcohol concentrations are usually equal to or greater than those of the cationic surfactants. The ternary system, surfactant/fatty alcohol/water, leads to a lamellar structure forming a percolated network giving rise to a gel. [2]
Quaternary ammonium cation. The R groups may be the same or different alkyl or aryl groups. Also, the R groups may be connected. In organic chemistry, quaternary ammonium cations, also known as quats, are positively-charged polyatomic ions of the structure [NR 4] +, where R is an alkyl group, an aryl group [1] or organyl group.
1,2-Dioleoyl-3-trimethylammonium propane (often abbreviated DOTAP or 18:1TAP) is a di-chain, or gemini, cationic surfactant. It is most commonly encountered as an active ingredient in certain fabric softeners. The pure material can also be used for the liposomal-transfection of DNA, RNA and other negatively charged molecules. [1]