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  2. Van Deemter equation - Wikipedia

    en.wikipedia.org/wiki/Van_Deemter_equation

    In liquid chromatography, the mobile phase velocity is taken as the exit velocity, that is, the ratio of the flow rate in ml/second to the cross-sectional area of the ‘column-exit flow path.’ For a packed column, the cross-sectional area of the column exit flow path is usually taken as 0.6 times the cross-sectional area of the column.

  3. Gradient - Wikipedia

    en.wikipedia.org/wiki/Gradient

    The gradient of F is then normal to the hypersurface. Similarly, an affine algebraic hypersurface may be defined by an equation F(x 1, ..., x n) = 0, where F is a polynomial. The gradient of F is zero at a singular point of the hypersurface (this is the definition of a singular point). At a non-singular point, it is a nonzero normal vector.

  4. Del in cylindrical and spherical coordinates - Wikipedia

    en.wikipedia.org/wiki/Del_in_cylindrical_and...

    This article uses the standard notation ISO 80000-2, which supersedes ISO 31-11, for spherical coordinates (other sources may reverse the definitions of θ and φ): . The polar angle is denoted by [,]: it is the angle between the z-axis and the radial vector connecting the origin to the point in question.

  5. Barzilai-Borwein method - Wikipedia

    en.wikipedia.org/wiki/Barzilai-Borwein_method

    The Barzilai-Borwein method [1] is an iterative gradient descent method for unconstrained optimization using either of two step sizes derived from the linear trend of the most recent two iterates. This method, and modifications, are globally convergent under mild conditions, [ 2 ] [ 3 ] and perform competitively with conjugate gradient methods ...

  6. Phase-field model - Wikipedia

    en.wikipedia.org/wiki/Phase-field_model

    Phase-field models are usually constructed in order to reproduce a given interfacial dynamics. For instance, in solidification problems the front dynamics is given by a diffusion equation for either concentration or temperature in the bulk and some boundary conditions at the interface (a local equilibrium condition and a conservation law), [14] which constitutes the sharp interface model.

  7. Path loss - Wikipedia

    en.wikipedia.org/wiki/Path_loss

    Path loss normally includes propagation losses caused by the natural expansion of the radio wave front in free space (which usually takes the shape of an ever-increasing sphere), absorption losses (sometimes called penetration losses), when the signal passes through media not transparent to electromagnetic waves, diffraction losses when part of the radiowave front is obstructed by an opaque ...

  8. McCabe–Thiele method - Wikipedia

    en.wikipedia.org/wiki/McCabe–Thiele_method

    The vapor-liquid equilibrium line (the curved line from (0,0) to (1,1) in Figure 1) represents the vapor phase composition for a given liquid phase composition at equilibrium. Vertical lines drawn from the horizontal axis up to the x = y line indicate the composition of the inlet feed stream, the composition of the top (distillate) product ...

  9. PSRK - Wikipedia

    en.wikipedia.org/wiki/PSRK

    PSRK (short for Predictive Soave–Redlich–Kwong) [1] is an estimation method for the calculation of phase equilibria of mixtures of chemical components. The original goal for the development of this method was to enable the estimation of properties of mixtures containing supercritical components.