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Oxygen fluoride(s), bromine oxide(s), iodine oxide(s) – analogous oxygen halide and halogen oxides Sulfur fluoride (s), sulfur chloride (s), sulfur bromide (s), sulfur iodide (s) – analogous sulfur halides, some of which are valence isoelectronic with chlorine oxides.
The earliest method of synthesis was to treat mercury(II) oxide with chlorine gas. [3] However, this method is expensive, as well as highly dangerous due to the risk of mercury poisoning. 2 Cl 2 + HgO → HgCl 2 + Cl 2 O. A safer and more convenient method of production is the reaction of chlorine gas with hydrated sodium carbonate at 20–30 ...
Chlorine monoxide is a chemical radical with the chemical formula ClO •. It plays an important role in the process of ozone depletion. In the stratosphere, chlorine atoms react with ozone molecules to form chlorine monoxide and oxygen. Cl • + O 3 → ClO • + O 2. This reaction causes the depletion of the ozone layer. [1]
Chlorine dioxide is approximately 10 times more soluble in water than elemental chlorine [13] but its solubility is very temperature-dependent. At partial pressures above 10 kPa (1.5 psi) [13] (or gas-phase concentrations greater than 10% volume in air at STP) of ClO 2 may explosively decompose into chlorine and oxygen. The decomposition can be ...
It was originally reported to exist as the monomeric chlorine trioxide ClO 3 in gas phase, [2] but was later shown to remain an oxygen-bridged dimer after evaporation and until thermal decomposition into chlorine perchlorate, Cl 2 O 4, and oxygen. [3] The compound ClO 3 was then rediscovered. [4]
Dichlorine heptoxide is a covalent compound consisting of two ClO 3 portions linked by an oxygen atom. It has an overall bent molecular geometry (C 2 symmetry), with a Cl−O−Cl angle of 118.6°. The chlorine–oxygen bond lengths are 1.709 Å in the central region and 1.405 Å within each ClO 3 cluster. [1]
The international pictogram for oxidizing chemicals. Dangerous goods label for oxidizing agents. An oxidizing agent (also known as an oxidant, oxidizer, electron recipient, or electron acceptor) is a substance in a redox chemical reaction that gains or "accepts"/"receives" an electron from a reducing agent (called the reductant, reducer, or electron donor).
Compounds containing oxygen in other oxidation states are very uncommon: − 1 ⁄ 2 (superoxides), − 1 ⁄ 3 , 0 (elemental, hypofluorous acid), + 1 ⁄ 2 , +1 (dioxygen difluoride), and +2 (oxygen difluoride). Oxygen is reactive and will form oxides with all other elements except the noble gases helium, neon, argon and krypton. [1]