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In Bohr's theory describing the energies of transitions or quantum jumps between orbital energy levels is able to explain these formula. For the hydrogen atom Bohr starts with his derived formula for the energy released as a free electron moves into a stable circular orbit indexed by : [28] = The energy difference between two such levels is ...
The de Broglie wavelength is the wavelength, λ, associated with a particle with momentum p through the Planck constant, h: =. Wave-like behavior of matter has been experimentally demonstrated, first for electrons in 1927 and for other elementary particles , neutral atoms and molecules in the years since.
The Bohr radius is one of a trio of related units of length, the other two being the reduced Compton wavelength of the electron (/) and the classical electron radius (). Any one of these constants can be written in terms of any of the others using the fine-structure constant α {\displaystyle \alpha } :
With de Broglie's suggestion of the existence of electron matter waves in 1924, and for a short time before the full 1926 Schrödinger equation treatment of hydrogen-like atoms, a Bohr electron "wavelength" could be seen to be a function of its momentum; so a Bohr orbiting electron was seen to orbit in a circle at a multiple of its half ...
The last expression in the first equation shows that the wavelength of light needed to ionize a hydrogen atom is 4π/α times the Bohr radius of the atom. The second equation is relevant because its value is the coefficient for the energy of the atomic orbitals of a hydrogen atom: E n = − h c R ∞ / n 2 {\displaystyle E_{n}=-hcR_{\infty }/n ...
In Bohr's conception of the atom, the integer Rydberg (and Balmer) n numbers represent electron orbitals at different integral distances from the atom. A frequency (or spectral energy) emitted in a transition from n 1 to n 2 therefore represents the photon energy emitted or absorbed when an electron makes a jump from orbital 1 to orbital 2.
The energy of an electron is determined by its orbit around the atom, The n = 0 orbit, commonly referred to as the ground state, has the lowest energy of all states in the system. In atomic physics and chemistry , an atomic electron transition (also called an atomic transition, quantum jump, or quantum leap) is an electron changing from one ...
The theory would have correctly explained the Zeeman effect, except for the issue of electron spin. Sommerfeld's model was much closer to the modern quantum mechanical picture than Bohr's. In the 1950s Joseph Keller updated Bohr–Sommerfeld quantization using Einstein's interpretation of 1917, [6] now known as Einstein–Brillouin–Keller method.