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Phenolphthalein (/ f ɛ ˈ n ɒ l (f) θ ə l iː n / [citation needed] feh-NOL(F)-thə-leen) is a chemical compound with the formula C 20 H 14 O 4 and is often written as "HIn", "HPh", "phph" or simply "Ph" in shorthand notation. Phenolphthalein is often used as an indicator in acid–base titrations.
The two electrons are supplied by phenolphthalein: HOOH + 2 e − + 2 H + → 2 H 2 O. The consumption of protons during the course of the reaction has the effect of raising the pH of the solution, but the amount of base produced is negligible compared to the amount of base already present in the reagent mixture.
Solution: The main components of a universal indicator, in the form of a solution, are thymol blue, methyl red, bromothymol blue, and phenolphthalein. This mixture is important because each component loses or gains protons depending upon the acidity or alkalinity of the solution being tested. It is beneficial to use this type of universal ...
Animation of a strong acid–strong base neutralization titration (using phenolphthalein).The equivalence point is marked in red. In chemistry, neutralization or neutralisation (see spelling differences) is a chemical reaction in which acid and a base react with an equivalent quantity of each other.
Phenolphthalein, a commonly used indicator in acid and base titration. The approximate pH during titration can be approximated by three kinds of calculations. Before beginning of titration, the concentration of [ H + ] {\displaystyle {\ce {[H+]}}} is calculated in an aqueous solution of weak acid before adding any base.
For example, if the concentration of the conjugate base is 10 times greater than the concentration of the acid, their ratio is 10:1, and consequently the pH is pK a + 1 or pK b + 1. Conversely, if a 10-fold excess of the acid occurs with respect to the base, the ratio is 1:10 and the pH is pK a − 1 or pK b − 1.
Its sharp and easily detectable colour changes makes phenolphthalein a valuable tool for determining the endpoint of acid-base titrations, as a precise pH change signifies the completion of the reaction. When a weak acid reacts with a weak base, the equivalence point solution will be basic if the base is stronger and acidic if the acid is stronger.
Thymolphthalein is a phthalein dye used as an acid–base indicator. Its transition range is around pH 9.3–10.5. Below this pH, it is colorless; above, it is blue. The molar extinction coefficient for the blue thymolphthalein dianion is 38,000 M −1 cm −1 at 595 nm. [2]