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Most liquids freeze by crystallization, formation of crystalline solid from the uniform liquid. This is a first-order thermodynamic phase transition, which means that as long as solid and liquid coexist, the temperature of the whole system remains very nearly equal to the melting point due to the slow removal of heat when in contact with air, which is a poor heat conductor.
Superfluid: A phase achieved by a few cryogenic liquids at extreme temperature at which they become able to flow without friction. A superfluid can flow up the side of an open container and down the outside. Placing a superfluid in a spinning container will result in quantized vortices.
In thermodynamics, the phase rule is a general principle governing multi-component, multi-phase systems in thermodynamic equilibrium.For a system without chemical reactions, it relates the number of freely varying intensive properties (F) to the number of components (C), the number of phases (P), and number of ways of performing work on the system (N): [1] [2] [3]: 123–125
Supercooling is the cooling of a liquid below its freezing point without it becoming solid. Freezing point depression is when a solution can be cooled below the freezing point of the corresponding pure liquid due to the presence of the solute ; an example of this is the freezing point depression that occurs when salt is added to pure water.
Fig. 6 The four stages in the cooling cycle of the GM cooler. The cycle can be divided in four steps, with Fig.6, as follows: The cycle starts with the low-pressure (LP) valve closed, the high-pressure (HP) valve open, and the displacer all the way to the right (so in the cold region). All the gas is at room temperature. From a to b.
There is also the peritectoid, a point where two solid phases combine into one solid phase during cooling. The inverse of this, when one solid phase transforms into two solid phases during cooling, is called the eutectoid. A complex phase diagram of great technological importance is that of the iron–carbon system for less than 7% carbon (see ...
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A condenser is designed to transfer heat from a working fluid (e.g. water in a steam power plant) to a secondary fluid or the surrounding air. The condenser relies on the efficient heat transfer that occurs during phase changes, in this case during the condensation of a vapor into a liquid. The vapor typically enters the condenser at a ...