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Lime softening (also known as lime buttering, lime-soda treatment, or Clark's process) [1] is a type of water treatment used for water softening, which uses the addition of limewater (calcium hydroxide) to remove hardness (deposits of calcium and magnesium salts) by precipitation.
In industrial scale water softening plants, the effluent flow from the re-generation process can precipitate scale that can interfere with sewage systems. [3] The slippery feeling associated with washing in soft water is caused by the weaker attraction of the soap to the water ions when the water has been stripped of its mineral content.
A precursor to the soda pulping process was the paper making process developed by Matthias Koops in 1801 which involved washing wood shavings in limewater, adding soda crystals and then boiling the mixture. [2] Soda pulping was one of the first chemical pulping methods and was invented in 1851 by Burgess (United States) and Watts (England).
A process flow diagram (PFD) is a diagram commonly used in chemical and process engineering to indicate the general flow of plant processes and equipment. The PFD displays the relationship between major equipment of a plant facility and does not show minor details such as piping details and designations.
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Caustic soda is limited to smaller combustion units because it is more expensive than lime, but it has the advantage that it forms a solution rather than a slurry. This makes it easier to operate. It produces a " spent caustic " solution of sodium sulfite /bisulfite (depending on the pH), or sodium sulfate that must be disposed of.