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Due to the large size of the La 3+ ion, La 2 O 3 adopts a hexagonal 7-coordinate structure that changes to the 6-coordinate structure of scandium oxide (Sc 2 O 3) and yttrium oxide (Y 2 O 3) at high temperature. When it reacts with water, lanthanum hydroxide is formed: [37] a lot of heat is evolved in the reaction and a hissing sound is heard.
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2 La + 3 S → La 2 S 3. It can also be prepared from the effect of hydrogen sulfide on lanthanum: 2 La + 3H 2 S → La 2 S 3 + 3 H 2. The effect of hydrogen sulfide on lanthanum oxide in the presence of reducing agents also produces lanthanum(III) sulfide: La 2 O 3 + 3 H 2 S + 3 C → La 2 S 3 + 3 CO 2 + 3 H 2
Print/export Download as PDF; Printable version; In other projects ... Lanthanum(III) iodate is an inorganic compound with the chemical formula La(IO 3) 3. Preparation
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Lanthanum hydroxide does not react much with alkaline substances, however is slightly soluble in acidic solution. [2] In temperatures above 330 °C it decomposes into lanthanum oxide hydroxide (LaOOH), which upon further heating decomposes into lanthanum oxide (La 2 O 3): [4]