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Although barium is a heavy metal, and its water-soluble compounds are often highly toxic, the low solubility of barium sulfate protects the patient from absorbing harmful amounts of the metal. Barium sulfate is also readily removed from the body, unlike Thorotrast, which it replaced.
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
The tables below provides information on the variation of solubility of different substances (mostly inorganic compounds) in water with temperature, at one atmosphere pressure. Units of solubility are given in grams of substance per 100 millilitres of water (g/100 ml), unless shown otherwise.
The solubility of a specific solute in a specific solvent is generally expressed as the concentration of a saturated solution of the two. [1] Any of the several ways of expressing concentration of solutions can be used, such as the mass, volume, or amount in moles of the solute for a specific mass, volume, or mole amount of the solvent or of the solution.
Historically, baryte was used for the production of barium hydroxide for sugar refining, and as a white pigment for textiles, paper, and paint. [3] Although baryte contains the toxic alkaline earth metal barium, it is not detrimental for human health, animals, plants and the environment because barium sulfate is extremely insoluble in water.
Its solubility in pure water is 7.32 x 10 −4 M. However in a solution that is 0.0200 M in barium nitrate, Ba(NO 3) 2, the increase in the common ion barium leads to a decrease in iodate ion concentration. The solubility is therefore reduced to 1.40 x 10 −4 M, about five times smaller. [1]
The water-soluble barium sulfide is the starting point for other compounds: treating BaS with oxygen produces the sulfate, with nitric acid the nitrate, with aqueous carbon dioxide the carbonate, and so on. [9]: 6 The nitrate can be thermally decomposed to yield the oxide.
Variations exist, for example, more ZnS-rich materials are produced when zinc chloride is added to the mixture of zinc sulfate and barium sulfide. [1] Barium sulfide is produced by carbothermic reduction of barium sulfate. Zinc sulfate is obtained from a variety of zinc products, often waste, by treatment with sulfuric acid.