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Branch point in a polymer. Polymer architecture in polymer science relates to the way branching leads to a deviation from a strictly linear polymer chain. [1] Branching may occur randomly or reactions may be designed so that specific architectures are targeted. [1] It is an important microstructural feature.
In chemistry and biology, a cross-link is a bond or a short sequence of bonds that links one polymer chain to another. These links may take the form of covalent bonds or ionic bonds and the polymers can be either synthetic polymers or natural polymers (such as proteins ).
Topological polymers, or polymer topology, could refer to a single polymeric chain with topological information or a polymer network with special junctions or connections. When the topology of a polymeric chain or network is investigated, the exact chemical composition is usually neglected, but the way of junctions and connections is more ...
In polymer chemistry, a structural unit is a building block of a polymer chain. It is the result of a monomer which has been polymerized into a long chain. There may be more than one structural unit in the repeat unit. When different monomers are polymerized, a copolymer is formed. It is a routine way of developing new properties for new materials.
A polymer's architecture affects many of its physical ... higher resistance of a polymer. Cross-linked ... awarded in the area of polymer science, ...
Flory–Stockmayer theory is a theory governing the cross-linking and gelation of step-growth polymers. [1] The Flory–Stockmayer theory represents an advancement from the Carothers equation, allowing for the identification of the gel point for polymer synthesis not at stoichiometric balance. [1]
After removal of the stimulus, the bonds reform and, in the ideal case, the original cross-link density is restored. This temporary decrease in cross-link density enables very fast topology rearrangements in dissociative CANs, such as viscous flow and stress relaxation, which allows the reprocessing of covalently cross-linked polymer networks.
The pioneer of synthetic polymer science, Wallace Carothers, developed a new means of making polyesters through step-growth polymerization in 1930s as a research group leader at DuPont. It was the first reaction designed and carried out with the specific purpose of creating high molecular weight polymer molecules, as well as the first ...