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Partition coefficient (K D) - The ratio of concentrations of a compound in two phases of a mixture of two immiscible solvents at equilibrium. Hall coefficient (electrical physics) - Relates a magnetic field applied to an element to the voltage created, the amount of current and the element thickness. It is a characteristic of the material from ...
where A and B are reactants C is a product a, b, and c are stoichiometric coefficients,. the reaction rate is often found to have the form: = [] [] Here is the reaction rate constant that depends on temperature, and [A] and [B] are the molar concentrations of substances A and B in moles per unit volume of solution, assuming the reaction is taking place throughout the volume of the ...
Charge transfer coefficient, and symmetry factor (symbols α and β, respectively) are two related parameters used in description of the kinetics of electrochemical reactions. They appear in the Butler–Volmer equation and related expressions.
D im is the mixture-averaged diffusion coefficient, c p is the specific heat capacity at constant pressure. In the field of fluid mechanics, many sources define the Lewis number to be the inverse of the above definition. [3] [4] The Lewis number can also be expressed in terms of the Prandtl number (Pr) and the Schmidt number (Sc): [5]
The general form of the Eyring–Polanyi equation somewhat resembles the Arrhenius equation: = ‡ where is the rate constant, ‡ is the Gibbs energy of activation, is the transmission coefficient, is the Boltzmann constant, is the temperature, and is the Planck constant.
A constant coefficient, also known as constant term or simply constant, is a quantity either implicitly attached to the zeroth power of a variable or not attached to other variables in an expression; for example, the constant coefficients of the expressions above are the number 3 and the parameter c, involved in 3=c ⋅ x 0.
Theoretical chemistry requires quantities from core physics, such as time, volume, temperature, and pressure.But the highly quantitative nature of physical chemistry, in a more specialized way than core physics, uses molar amounts of substance rather than simply counting numbers; this leads to the specialized definitions in this article.
In chemistry, the rate of a chemical reaction is influenced by many different factors, such as temperature, pH, reactant, the concentration of products, and other effectors. The degree to which these factors change the reaction rate is described by the elasticity coefficient. This coefficient is defined as follows: