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Water is the medium of the oceans, the medium which carries all the substances and elements involved in the marine biogeochemical cycles. Water as found in nature almost always includes dissolved substances, so water has been described as the "universal solvent" for its ability to dissolve so many substances.
The solubility of gas obeys Henry's law, that is, the amount of a dissolved gas in a liquid is proportional to its partial pressure. Therefore, placing a solution under reduced pressure makes the dissolved gas less soluble. Sonication and stirring under reduced pressure can usually enhance the efficiency.
Marine chemistry, also known as ocean chemistry or chemical oceanography, is the study of the chemical composition and processes of the world’s oceans, including the interactions between seawater, the atmosphere, the seafloor, and marine organisms. [2]
dissolved gases – oxygen levels in particular, can be increased by wave actions and decreased during algal blooms; acidity – this is partly to do with dissolved gases above, since the acidity of the ocean is largely controlled by how much carbon dioxide is in the water.
In simple words, we can say that the partial pressure of a gas in vapour phase is directly proportional to the mole fraction of a gas in solution. An example where Henry's law is at play is the depth-dependent dissolution of oxygen and nitrogen in the blood of underwater divers that changes during decompression, going to decompression sickness.
Inert gas such as nitrogen or helium continues to be taken up until the gas dissolved in the diver is in a state of equilibrium with the breathing gas in the diver's lungs, at which point the diver is saturated for that depth and breathing mixture, or the depth, and therefore the pressure, is changed, or the partial pressures of the gases are ...
However, unlike many other gases (oxygen for instance), it reacts with water and forms a balance of several ionic and non-ionic species (collectively known as dissolved inorganic carbon, or DIC). These are dissolved free carbon dioxide (CO 2 (aq)), carbonic acid (H 2 CO 3), bicarbonate (HCO 3 −) and carbonate (CO 3 2−), and they interact ...
CaCO 3 is supersatured in the great majority of ocean surface waters and undersaturated at depth, [10] meaning the shells are more likely to dissolve as they sink to ocean depths. CaCO 3 can also be dissolved through metabolic dissolution (i.e. can be used as food and excreted) and thus deep ocean sediments have very little calcium carbonate. [16]