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Tantalum is a chemical element; it has symbol Ta and atomic number 73. Previously known as tantalium, [citation needed] it is named after Tantalus, a figure in Greek mythology. [11] Tantalum is a very hard, ductile, lustrous, blue-gray transition metal that is highly corrosion-resistant.
Coltan is the colloquial name for the mineral columbite-tantalum ("col-tan"). In the early 21st century coltan mining is associated with human rights violations such as child labour, systematic exploitation of the population by governments or militant groups, exposure to toxic chemicals and other hazards as a result of lax environmental protection, and general safety laws and regulations. [1]
Tantalum(V) chloride, also known as tantalum pentachloride, is an inorganic compound with the formula TaCl 5.It takes the form of a white powder and is commonly used as a starting material in tantalum chemistry.
Potassium heptafluorotantalate is an intermediate in the industrial production of metallic tantalum. Its production involves leaching tantalum ores, such as columbite and tantalite, with hydrofluoric acid and sulfuric acid to produce the water-soluble hydrogen heptafluorotantalate. [2] Ta 2 O 5 + 14 HF → 2 H 2 [TaF 7] + 5 H 2 O
With the addition of squarate or perchlorate, the tantalum complex dimerises in acetonitrile, with their respective chelating ligands bridging the Ta centres. These seven-coordinate complexes of the form TaMe 3 L 2, where L is a bidentate monoanion, are markedly more thermally stable than their precursor, decomposing in the range 80 - 120°C.
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Tris(silox)tantalum, Ta(SiO t Bu 3) 3, is an organotantalum complex bound with three siloxide (this siloxide has three tert-butyl groups attached to silicon, attached via oxygen (t Bu 3 SiO-)) ligands. The tantalum center has a d-electron count of 2 and an oxidation state of III. The complex is trigonal planar whose point group is assigned as D 3h.
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