Search results
Results from the WOW.Com Content Network
Then an excess but fixed volume of sulfanilamide and N-(1-naphthyl)ethylenediamine dihydrochloride solution is added. With nitrous acid as the limiting reagent, the azo coupling reaction produces an azo dye quantitatively with respect to the nitrite ions: The diazo compound formed accounts for the red coloration typical for a positive result.
The sulfonic acid derivatives of 1-naphthylamine are used for the preparation of azo dye.These compounds possess the important property of dyeing unmordanted cotton.. An important derivative is naphthionic acid (1-aminonaphthalene-4-sulfonic acid), which is produced by heating 1-naphthylamine and sulfuric acid to 170–180 °C in the presence of crystallized oxalic acid.
1-Naphthol biodegrades via formation of 1-naphthol-3,4-oxide, which converts to 1,4-naphthoquinone. [3] The 4-position of 1-naphthol is susceptible to electrophilic attack. This regioselective reaction is exploited in the preparation of diazo dyes, which are form using diazonium salts. Reduction of the diazo derivatives gives 4-amino-1-naphthol ...
The organic reaction also goes by the name Bucherer-Lepetit reaction or (incorrectly) the Bucherer-Le Petit reaction. The reaction is used to convert 1,7-dihydroxynaphthalene into 7-amino-1-naphthol and 1-aminonaphthalene-4-sulfonic acid into 1-hydroxynaphthalene-4-sulfonic acid. It is also useful for transamination reactions of 2 ...
In organic chemistry, the Mannich reaction is a three-component organic reaction that involves the amino alkylation of an acidic proton next to a carbonyl (C=O) functional group by formaldehyde (H−CHO) and a primary or secondary amine (−NH 2) or ammonia (NH 3). [1] The final product is a β-amino-carbonyl compound also known as a Mannich base.
There were a number of senators, including Trump allies like Sen. Lindsey Graham, R-S.C., and Sen. Ted Cruz, R-Texas, who forcefully made the case for a two-bill solution while in the room with Trump.
Michael Brewer, one-half of Brewer & Shipley, has died. He was 80. On Tuesday, Dec. 17, his musical partner, Tom Shipley, confirmed the news of his death on Facebook
For weak acids or bases, the heat of neutralization is pH-dependent. [1] In the absence of any added mineral acid or alkali, some heat is required for complete dissociation. The total heat evolved during neutralization will be smaller. e.g. + +; = / at 25°C. The heat of ionization for this reaction is equal to (–12 + 57.3) = 45.3 kJ/mol at ...