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A stable binary hydride and the simplest pnictogen hydride, ammonia is a colourless gas with a distinctive pungent smell. Biologically, it is a common nitrogenous waste, and it contributes significantly to the nutritional needs of terrestrial organisms by serving as a precursor to fertilisers. [13]
Pnictogen hydrides or hydrogen pnictides are binary compounds of hydrogen with pnictogen (/ ˈ p n ɪ k t ə dʒ ə n / or / ˈ n ɪ k t ə dʒ ə n /; from Ancient Greek: πνῑ́γω "to choke" and -gen, "generator") atoms (elements of group 15: nitrogen, phosphorus, arsenic, antimony, bismuth, and moscovium) covalently bonded to hydrogen.
In chemistry, a pnictogen bond (PnB) is a non-covalent interaction, occurring where there is a net attractive force between an electrophilic region on a 'donor' pnictogen atom (Pn) in a molecule, and a nucleophilic region on an 'acceptor' atom, which may be in the same or another molecule. [1]
These are in the form of RE a M b Pn c, where M is a carbon group or boron group element and Pn is any pnictogen except nitrogen. These compounds are between ionic and covalent compounds and thus have unusual bonding properties. [4] These elements are also noted for their stability in compounds due to their tendency to form covalent double ...
It is a colorless, volatile, and explosive liquid at room temperature and pressure. It is a compound of nitrogen and hydrogen, and is therefore a pnictogen hydride. It was first isolated in 1890 by Theodor Curtius. [4] The acid has few applications, but its conjugate base, the azide ion, is useful in specialized processes.
Binary hydrogen compounds in group 1 are the ionic hydrides (also called saline hydrides) wherein hydrogen is bound electrostatically. Because hydrogen is located somewhat centrally in an electronegative sense, it is necessary for the counterion to be exceptionally electropositive for the hydride to possibly be accurately described as truly behaving ionic.
In chemistry, an onium ion is a cation formally obtained by the protonation of mononuclear parent hydride of a pnictogen (group 15 of the periodic table), chalcogen (group 16), or halogen (group 17). The oldest-known onium ion, and the namesake for the class, is ammonium , NH + 4 , the protonated derivative of ammonia , NH 3 .
Ionic hydrides are used as bases and, occasionally, as reducing reagents in organic synthesis. [12] C 6 H 5 C(O)CH 3 + KH → C 6 H 5 C(O)CH 2 K + H 2. Typical solvents for such reactions are ethers. Water and other protic solvents cannot serve as a medium for ionic hydrides because the hydride ion is a stronger base than hydroxide and most ...