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tert-Butyl bromide (also referred to as 2-bromo-2-methylpropane) is an organic compound with the formula Me 3 CBr (Me = methyl). The molecule features a tert-butyl group attached to a bromide substituent. This organobromine compound is used as a standard reagent in synthetic organic chemistry. It is a colorless liquid.
The effect of the tert-butyl group on the progress of a chemical reaction is called the Thorpe–Ingold effect illustrated in the Diels-Alder reaction below. Compared to a hydrogen substituent, the tert-butyl substituent accelerates the reaction rate by a factor of 240. [2] tert-Butyl effect. The tert-butyl effect is an example of steric hindrance.
Such reagents are used to attach butyl groups to various substrates. 1-Bromobutane is the precursor to n -butyllithium : [ 4 ] 2 Li + C 4 H 9 X → C 4 H 9 Li + LiX
This page contains tables of azeotrope data for various binary and ternary mixtures of solvents. The data include the composition of a mixture by weight (in binary azeotropes, when only one fraction is given, it is the fraction of the second component), the boiling point (b.p.) of a component, the boiling point of a mixture, and the specific gravity of the mixture.
The molecular formula C 4 H 9 Br, (molar mass: 137.02 g/mol, exact mass: 135.9888 u) may refer to: 1-Bromobutane; 2-Bromobutane; tert-Butyl bromide; 1-bromo-2 ...
1-Bromo-2-methylpropane (isobutyl bromide) 2-Bromo-2-methylpropane (tert-butyl bromide) This page was last edited on 5 February 2022 ...
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An example of a reaction taking place with an S N 1 reaction mechanism is the hydrolysis of tert-butyl bromide forming tert-butanol: This S N 1 reaction takes place in three steps: Formation of a tert-butyl carbocation by separation of a leaving group (a bromide anion) from the carbon atom: this step is slow. [5] Recombination of carbocation ...