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Polyatomic ions often are useful in the context of acid–base chemistry and in the formation of salts. Often, a polyatomic ion can be considered as the conjugate acid or base of a neutral molecule. For example, the conjugate base of sulfuric acid (H 2 SO 4) is the polyatomic hydrogen sulfate anion (HSO − 4).
Ions consisting of only a single atom are termed atomic or monatomic ions, while two or more atoms form molecular ions or polyatomic ions. In the case of physical ionization in a fluid (gas or liquid), "ion pairs" are created by spontaneous molecule collisions, where each generated pair consists of a free electron and a positive ion. [5]
The cation is always named first. Ions can be metals, non-metals or polyatomic ions. Therefore, the name of the metal or positive polyatomic ion is followed by the name of the non-metal or negative polyatomic ion. The positive ion retains its element name whereas for a single non-metal anion the ending is changed to -ide.
Each ion can be either monatomic (termed simple ion), such as sodium (Na +) and chloride (Cl −) in sodium chloride, or polyatomic, such as ammonium (NH + 4) and carbonate (CO 2− 3) ions in ammonium carbonate. Salts containing basic ions hydroxide (OH −) or oxide (O 2−) are classified as bases, such as sodium hydroxide and potassium oxide.
For the compound, SnO 2, the tin ion is Sn 4+ (balancing out the 4− charge on the two O 2− anions), and because this is a higher oxidation state than the alternative (Sn 2+), this compound is termed stannic oxide. Some ionic compounds contain polyatomic ions, which are charged entities containing two or more covalently bonded types of atoms ...
Most polyhalogen ions are intensely colored, with deepened color as the atomic weight of the constituent element increases. The well-known starch-iodine complex has a deep blue color due to the linear [I 5] − ions present in the amylose helix. [4] Some colors of the common species were listed below: [3]
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Types of peroxides, from top to bottom: peroxide ion, organic peroxide, organic hydroperoxide, peracid. The peroxide group is marked in blue. R, R 1 and R 2 mark hydrocarbon moieties. The most common peroxide is hydrogen peroxide (H 2 O 2), colloquially known simply as "peroxide". It is marketed as solutions in water at various concentrations.