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Graphene quantum dots (GQDs) are graphene nanoparticles with a size less than 100 nm. [1] Due to their exceptional properties such as low toxicity, stable photoluminescence , chemical stability and pronounced quantum confinement effect, GQDs are considered as a novel material for biological, opto-electronics, energy and environmental applications.
A graphene quantum dot (GQD) is a graphene fragment with a size lesser than 100 nm. The properties of GQDs are different from bulk graphene due to the quantum confinement effects which only become apparent when the size is smaller than 100 nm. [214] [215] [216]
Graphene doped with various gaseous species (both acceptors and donors) can be returned to an undoped state by gentle heating in vacuum. [22] [24] Even for dopant concentrations in excess of 10 12 cm −2 carrier mobility exhibits no observable change. [24] Graphene doped with potassium in ultra-high vacuum at low temperature can reduce ...
Research is exploring the creation of quantum dots by changing the width of GNRs at select points along the ribbon, creating quantum confinement. [27] [20] Heterojunctions inside single graphene nanoribbons have been realized, among which structures that have been shown to function as tunnel barriers.
Graphene quantum dots have also been blended with organic electronic materials to improve efficiency and lower cost in photovoltaic devices and organic light emitting diodes compared to graphene sheets. These graphene quantum dots were functionalized with organic ligands that experience photoluminescence from UV–visible absorption. [103]
Pages in category "Quantum dots" The following 19 pages are in this category, out of 19 total. ... Graphene quantum dot; H. Hydrogel encapsulation of quantum dots; K.
Graphene quantum dots (GQDs) keep all dimensions less than 10 nm. Their size and edge crystallography govern their electrical, magnetic, optical, and chemical properties. GQDs can be produced via graphite nanotomy [ 85 ] or via bottom-up, solution-based routes ( Diels-Alder, cyclotrimerization and/or cyclodehydrogenation reactions ). [ 86 ]
Quantum dots are popular alternatives to organic dyes as fluorescent labels for biological imaging and sensing due to their small size, tuneable emission, and photostability. The luminescent properties of quantum dots arise from exciton decay (recombination of electron hole pairs) which can proceed through a radiative or nonradiative pathway.
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