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The sulfonic acid derivatives of 1-naphthylamine are used for the preparation of azo dye.These compounds possess the important property of dyeing unmordanted cotton.. An important derivative is naphthionic acid (1-aminonaphthalene-4-sulfonic acid), which is produced by heating 1-naphthylamine and sulfuric acid to 170–180 °C in the presence of crystallized oxalic acid.
Then an excess but fixed volume of sulfanilamide and N-(1-naphthyl)ethylenediamine dihydrochloride solution is added. With nitrous acid as the limiting reagent, the azo coupling reaction produces an azo dye quantitatively with respect to the nitrite ions: The diazo compound formed accounts for the red coloration typical for a positive result.
1-Naphthol, or α-naphthol, is a organic compound with the formula C 10 H 7 OH. It is a fluorescent white solid. 1-Naphthol differs from its isomer 2-naphthol by the location of the hydroxyl group on the naphthalene ring.
The organic reaction also goes by the name Bucherer-Lepetit reaction or (incorrectly) the Bucherer-Le Petit reaction. The reaction is used to convert 1,7-dihydroxynaphthalene into 7-amino-1-naphthol and 1-aminonaphthalene-4-sulfonic acid into 1-hydroxynaphthalene-4-sulfonic acid. It is also useful for transamination reactions of 2 ...
A practical synthesis involves the tin/HCl-reduction of the naphthalene-1-sulfonyl chloride. [1] 1-Naphthalenethiol can also be prepared from 1-bromonaphthalene by Pd-catalyzed reaction with the silylthiolate i Pr 3 SiSK followed by hydrolysis of the silathioether. [2] It was first prepared from the Grignard reagent generated from 1 ...
Like other simple aliphatic amines, ethylamine is a weak base: the pK a of [CH 3 CH 2 NH 3] + has been determined to be 10.8 [8] [9] Ethylamine undergoes the reactions anticipated for a primary alkyl amine, such as acylation and protonation. Reaction with sulfuryl chloride followed by oxidation of the sulfonamide give diethyldiazene, EtN=NEt. [10]
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The bonds C1−C2, C3−C4, C5−C6 and C7−C8 are about 1.37 Å (137 pm) in length, whereas the other carbon–carbon bonds are about 1.42 Å (142 pm) long. This difference, established by X-ray diffraction , [ 21 ] is consistent with the valence bond model in naphthalene and in particular, with the theorem of cross-conjugation .