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The term ‘acid sulfate soils’ (ASS) was coined by the Working Party on Nomenclature and Methods for the first International Symposium on Acid Sulfate Soils (1972, Wageningen) to mean soils that contain, or have the potential to produce, sulfuric acid in quantities that cause significant and long-lasting changes in key soil properties. [22]
Soil acidification is the buildup of hydrogen cations, which reduces the soil pH. Chemically, this happens when a proton donor gets added to the soil. The donor can be an acid, such as nitric acid, sulfuric acid, or carbonic acid. It can also be a compound such as aluminium sulfate, which reacts in the soil to release protons.
The pH of an alkaline soil can be reduced by adding acidifying agents or acidic organic materials. Elemental sulfur (90–99% S) has been used at application rates of 300–500 kg/ha (270–450 lb/acre) – it slowly oxidises in the soil to form sulfuric acid.
Sulfuric acid is a very important commodity chemical; a country's sulfuric acid production is a good indicator of its industrial strength. [10] Many methods for its production are known, including the contact process, the wet sulfuric acid process, and the lead chamber process. [11] Sulfuric acid is also a key substance in the chemical industry.
Example Bjerrum plot: Change in carbonate system of seawater from ocean acidification.. A Bjerrum plot (named after Niels Bjerrum), sometimes also known as a Sillén diagram (after Lars Gunnar Sillén), or a Hägg diagram (after Gunnar Hägg) [1] is a graph of the concentrations of the different species of a polyprotic acid in a solution, as a function of pH, [2] when the solution is at ...
Sulfate is an inert anion, so nature activates it by the formation of ester derivative of adenosine 5'-phosphosulfate (APS) and 3'-phosphoadenosine-5'-phosphosulfate (PAPS). Many organisms utilize these reactions for metabolic purposes or for the biosynthesis of sulfur compounds required for life. [ 9 ]
Soil formation, also known as pedogenesis, is the process of soil genesis as regulated by the effects of place, environment, and history. Biogeochemical processes act to both create and destroy order ( anisotropy ) within soils.
However, SO 3 added to concentrated sulfuric acid readily dissolves, forming oleum which can then be diluted with water to produce additional concentrated sulfuric acid. [4] Typically, above concentrations of 98.3%, sulfuric acid will undergo a spontaneous decomposition into sulfur trioxide and water H 2 SO 4 ⇌ SO 3 + H 2 O