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An enthalpy–entropy chart, also known as the H–S chart or Mollier diagram, plots the total heat against entropy, [1] describing the enthalpy of a thermodynamic system. [2] A typical chart covers a pressure range of 0.01–1000 bar , and temperatures up to 800 degrees Celsius . [ 3 ]
The underlying psychrometric parameter data for the psychrometric chart and the Mollier diagram are identical. At first glance there is little resemblance between the charts, but if the chart is rotated by ninety degrees and looked at in a mirror the resemblance becomes apparent. The Mollier diagram coordinates are enthalpy and humidity ratio.
The three diagrams are constructed from the P–alpha diagram by using appropriate coordinate transformations. Not a thermodynamic diagram in a strict sense, since it does not display the energy–area equivalence, is the Stüve diagram; But due to its simpler construction it is preferred in education. [citation needed]
The high-pressure liquid enters a boiler, where it is heated at constant pressure by an external heat source to become a dry saturated vapour. The input energy required can be easily calculated graphically, using an enthalpy–entropy chart (h–s chart, or Mollier diagram), or numerically, using steam tables or software. Process 3–4
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The liquid–liquid critical point of a solution, which occurs at the critical solution temperature, occurs at the limit of the two-phase region of the phase diagram. In other words, it is the point at which an infinitesimal change in some thermodynamic variable (such as temperature or pressure) leads to separation of the mixture into two ...
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Richard Mollier (German: [mɔˈli̯eː]; 30 November 1863, Triest – 13 March 1935, Dresden) was a German professor of Applied Physics and Mechanics in Göttingen and Dresden, a pioneer of experimental research in thermodynamics, particularly for water, steam, and moist air.