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Liquid carbon dioxide is the liquid state of carbon dioxide (CO 2 ), which cannot occur under atmospheric pressure. It can only exist at a pressure above 5.1 atm (5.2 bar; 75 psi), under 31.1 °C (88.0 °F) (temperature of critical point ) and above −56.6 °C (−69.9 °F) (temperature of triple point ). [ 1 ]
Carbon dioxide: 3.640 0.04267 Carbon disulfide: 11.77 0.07685 Carbon monoxide: 1.505 0.0398500 Carbon tetrachloride: ... Water: 5.536 0.03049 Xenon: 4.250 0.05105
‡ Second column of table indicates solubility at each given temperature in volume of CO 2 as it would be measured at 101.3 kPa and 0 °C per volume of water. The solubility is given for "pure water", i.e., water which contain only CO 2. This water is going to be acidic. For example, at 25 °C the pH of 3.9 is expected (see carbonic acid).
The symmetry of a carbon dioxide molecule is linear and centrosymmetric at its equilibrium geometry. The length of the carbon–oxygen bond in carbon dioxide is 116.3 pm, noticeably shorter than the roughly 140 pm length of a typical single C–O bond, and shorter than most other C–O multiply bonded functional groups such as carbonyls. [19]
Note that the especially high molar values, as for paraffin, gasoline, water and ammonia, result from calculating specific heats in terms of moles of molecules. If specific heat is expressed per mole of atoms for these substances, none of the constant-volume values exceed, to any large extent, the theoretical Dulong–Petit limit of 25 J⋅mol ...
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Nitrous oxide has similar physical behavior to carbon dioxide, but is a powerful oxidizer in its supercritical state. Supercritical water is inconvenient due to possible heat damage to a sample at its critical point temperature (647 K, 374 °C) and corrosiveness of water at such high temperatures and pressures (22.064 MPa, 3,212 psi).