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The chloralkali process (also chlor-alkali and chlor alkali) is an industrial process for the electrolysis of sodium chloride (NaCl) solutions. It is the technology used to produce chlorine and sodium hydroxide (caustic soda), [ 1 ] which are commodity chemicals required by industry.
Another earlier process to produce chlorine was to heat brine with acid and manganese dioxide. 2 NaCl + 2H 2 SO 4 + MnO 2 → Na 2 SO 4 + MnSO 4 + 2 H 2 O + Cl 2. Using this process, chemist Carl Wilhelm Scheele was the first to isolate chlorine in a laboratory. The manganese can be recovered by the Weldon process. [11]
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The chlor-alkali industry is a major consumer of the world's energy budget. This process converts concentrated sodium chloride solutions into chlorine and sodium hydroxide, which are used to make many other materials and chemicals. The process involves two parallel reactions: 2 Cl − → Cl 2 + 2 e − 2 H 2 O + 2 e − → H 2 + 2 OH −
The first type, shown on the right and left of the diagram, uses an electrolyte of sodium chloride solution, a graphite anode (A), and a mercury cathode (M). The other type of cell, shown in the center of the diagram, uses an electrolyte of sodium hydroxide solution, a mercury anode (M), and an iron cathode (D). The mercury electrode is common ...
The process of electrochlorination is a simple application based on the chloralkali process (in an unpartitioned cell). It is the electrolysis of saltwater to produce a chlorinated solution. The first step is removing any solids from the saltwater. Next, the saltwater streams through an electrolyzer cell's channel of decreasing thickness.
The Deacon process, invented by Henry Deacon, is a process used during the manufacture of alkalis (the initial end product was sodium carbonate) by the Leblanc process. Hydrogen chloride gas was converted to chlorine gas, which was then used to manufacture a commercially valuable bleaching powder , and at the same time the emission of waste ...
This precipitation reaction is used in chlor-alkali plants to control the sulfate concentration in the feed brine for electrolysis. Oxalate effects a similar reaction: BaCl 2 + Na 2 C 2 O 4 → 2 NaCl + BaC 2 O 4. When it is mixed with sodium hydroxide, it gives barium hydroxide, which is moderately soluble in water. BaCl 2 + 2 NaOH → 2 NaCl ...