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Diagram of the Stokes shift between absorption and emission light spectra. Stokes shift is the difference (in energy, wavenumber or frequency units) between positions of the band maxima of the absorption and emission spectra (fluorescence and Raman being two examples) of the same electronic transition. [1]
The most straightforward approach to absorption spectroscopy is to generate radiation with a source, measure a reference spectrum of that radiation with a detector and then re-measure the sample spectrum after placing the material of interest in between the source and detector. The two measured spectra can then be combined to determine the ...
The changes between these levels are called "transitions" and are plotted on the Jablonski diagram. Radiative transitions involve either the absorption or emission of a photon. As mentioned above, these transitions are denoted with solid arrows with their tails at the initial energy level and their tips at the final energy level.
Schematic representation of the absorption line shape of an electronic excitation. The narrow component at the frequency ω′ is the zero-phonon line and the broader feature is the phonon sideband. In emission, the relative positions of the two components are mirrored about the center of the zero-phonon line at ω′.
This is reflected in the absorption or emission spectrum of the solute as differences in the position, intensity, and shape of the spectroscopic bands. When the spectroscopic band occurs in the visible part of the electromagnetic spectrum, solvatochromism is observed as a change of colour. This is illustrated by Reichardt's dye, as shown in the ...
The emission spectrum of a chemical element or chemical compound is the spectrum of frequencies of electromagnetic radiation emitted due to electrons making a transition from a high energy state to a lower energy state. The photon energy of the emitted photons is equal to the energy difference between the two states. There are many possible ...
Atomic absorption spectroscopy (AAS) is a spectroanalytical procedure for the quantitative measurement of chemical elements. AAS is based on the absorption of light by free metallic ions that have been atomized from a sample. An alternative technique is atomic emission spectroscopy (AES).
The classical example of a discrete spectrum (for which the term was first used) is the characteristic set of discrete spectral lines seen in the emission spectrum and absorption spectrum of isolated atoms of a chemical element, which only absorb and emit light at particular wavelengths. The technique of spectroscopy is based on this phenomenon.