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  2. Covalent bond - Wikipedia

    en.wikipedia.org/wiki/Covalent_bond

    A double bond between two given atoms consists of one σ and one π bond, and a triple bond is one σ and two π bonds. [8] Covalent bonds are also affected by the electronegativity of the connected atoms which determines the chemical polarity of the bond. Two atoms with equal electronegativity will make nonpolar covalent bonds such as H–H.

  3. Cohesion (chemistry) - Wikipedia

    en.wikipedia.org/wiki/Cohesion_(chemistry)

    The polarity is due to the electronegativity of the atom of oxygen: oxygen is more electronegative than the atoms of hydrogen, so the electrons they share through the covalent bonds are more often close to oxygen rather than hydrogen. These are called polar covalent bonds, covalent bonds between atoms that thus become oppositely charged. [1]

  4. Bonding in solids - Wikipedia

    en.wikipedia.org/wiki/Bonding_in_solids

    As noted above, covalent and ionic bonds form a continuum between shared and transferred electrons; covalent and weak bonds form a continuum between shared and unshared electrons. In addition, molecules can be polar, or have polar groups, and the resulting regions of positive and negative charge can interact to produce electrostatic bonding ...

  5. Molecular solid - Wikipedia

    en.wikipedia.org/wiki/Molecular_solid

    When it is converted to the covalent red phosphorus, the density goes to 2.2–2.4 g/cm 3 and melting point to 590 °C, and when white phosphorus is transformed into the (also covalent) black phosphorus, the density becomes 2.69–3.8 g/cm 3 and melting temperature ~200 °C. Both red and black phosphorus forms are significantly harder than ...

  6. Valence bond theory - Wikipedia

    en.wikipedia.org/wiki/Valence_bond_theory

    This theory is used to explain the covalent bond formation in many molecules. sp 3 hybridization in methane forms four equivalent sigma bonds with tetrahedral geometry. For example, in the case of the F 2 molecule, the F−F bond is formed by the overlap of p z orbitals of the two F atoms

  7. Fajans' rules - Wikipedia

    en.wikipedia.org/wiki/Fajans'_rules

    In inorganic chemistry, Fajans' rules, formulated by Kazimierz Fajans in 1923, [1] [2] [3] are used to predict whether a chemical bond will be covalent or ionic, and depend on the charge on the cation and the relative sizes of the cation and anion. They can be summarized in the following table:

  8. Heterolysis (chemistry) - Wikipedia

    en.wikipedia.org/wiki/Heterolysis_(chemistry)

    The discovery and categorization of heterolytic bond fission was clearly dependent on the discovery and categorization of the chemical bond. In 1916, chemist Gilbert N. Lewis developed the concept of the electron-pair bond, in which two atoms share one to six electrons, thus forming the single electron bond, a single bond, a double bond, or a triple bond. [3]

  9. Molecular binding - Wikipedia

    en.wikipedia.org/wiki/Molecular_binding

    Reversible covalent – a chemical bond is formed, however the free energy difference separating the noncovalently-bonded reactants from bonded product is near equilibrium and the activation barrier is relatively low such that the reverse reaction which cleaves the chemical bond easily occurs; Irreversible covalent – a chemical bond is formed ...

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